Atomic Structure, Chemical Bonding, and Ionic Interactions

Atomic Structure, Atomic Number, and Electron Shells

  • Subatomic Particle Properties:

    • Protons: positively charged subatomic particles (++).

    • Neutrons: uncharged, neutral subatomic particles.

    • Electrons: negatively charged subatomic particles (-).

  • Atomic Number:

    • Each chemical element contains a unique, specific number of protons; this count is defined as the atomic number.

    • Atoms are electrically neutral overall because the number of protons equals the number of electrons.

  • Electron Shell Distribution and the Octet Rule:

    • First electron shell: holds a maximum capacity of 22 electrons.

    • Subsequent electron shells: every shell after the first fits up to 88 electrons (8e8\,e^-).

    • Chemical reactivity principle: atoms react with other atoms to fill their outer electron shell (valence shell) and achieve stability.

  • Structural Example — Nitrogen Atom:

    • Total atomic content: 77 electrons, 77 protons, and 77 neutrons.

    • Electron shell distribution: 22 electrons in the first electron shell and 55 electrons in the second electron shell.

    • Orbital distribution details:

    • First electron shell: filled with 22 electrons.

    • Second electron shell ss orbital: filled with 22 electrons (a pair of electrons).

    • Second electron shell pp orbitals: contains three distinct pp orbitals, each holding 11 single electron.

Simplified depiction and orbital model of a nitrogen atom

Atomic Mass and Isotopes

  • Atomic Mass Calculation:

    • Under standard conditions, the number of protons equals the number of neutrons in an atom.

    • Formula: Atomic mass=protons+neutrons\text{Atomic mass} = \text{protons} + \text{neutrons}

  • Isotopes and Radioisotopes:

    • Isotopes are structural variations of chemical elements that share the same number of protons but differ in the number of neutrons.

    • Radioisotopes: unstable isotopes that undergo spontaneous decay and emit radiation/energy.

  • Gram Atomic Mass:

    • Defined as the exact amount of an element in grams that equals the numerical value of its atomic weight.

Ions and Biological Ionic Forms

  • Ion Formation:

    • Ions are created when neutral atoms gain or lose electrons, thereby acquiring a net electrical charge.

    • Cations: positively charged ions formed when an atom loses electrons (e.g., sodium losing an electron: NaNa++eNa \rightarrow Na^+ + e^-).

    • Anions: negatively charged ions formed when an atom gains electrons (e.g., chlorine gaining an electron: Cl+eClCl + e^- \rightarrow Cl^-).

  • Primary Ions Encountered in Human Physiology:

    • Hydrogen (HH): forms Hydrogen ion (H+H^+) by losing 11 electron.

    • Sodium (NaNa): forms Sodium ion (Na+Na^+) by losing 11 electron.

    • Potassium (KK): forms Potassium ion (K+K^+) by losing 11 electron.

    • Chlorine (ClCl): forms Chloride ion (ClCl^-) by gaining 11 electron.

    • Magnesium (MgMg): forms Magnesium ion (Mg2+Mg^{2+}) by losing 22 electrons.

    • Calcium (CaCa): forms Calcium ion (Ca2+Ca^{2+}) by losing 22 electrons.

Table of ionic forms of elements frequently encountered in the body

Molecules and Chemical Bonds

  • Molecules:

    • Formed when two or more atoms are joined together by chemical bonds.

    • Represented chemical formulas denote their constituent atoms and exact atomic ratios (e.g., glucose is represented as C6H12O6C_6H_{12}O_6).

  • Chemical Bond Classification:

    • Covalent Bonds: represent the strongest type of chemical bond, formed when one or more pairs of electrons in outer orbitals are shared between atoms.

    • Polar Covalent Bonds:

    • Characterized by unequal electron sharing between bonded atoms due to differences in electronegativity.

    • Produces a dipole moment, denoted by the symbol δ\delta (slight charge).

    • The more electronegative atom acquires a slight negative charge (δ\delta^-), while the less electronegative atom acquires a slight positive charge (δ+\delta^+) (e.g., hydroxyl groups where oxygen holds δ\delta^- relative to hydrogen holding δ+\delta^+).

    • Non-Polar Covalent Bonds:

    • Characterized by completely equal sharing of electrons between identical or similarly electronegative atoms, resulting in no charge separation.