15 Greenhouse gases and the Carbon Cycle
Carbon Dioxide and Methane
- When shortwave radiation from the sun strikes the Earth's surface it is absorbed and re-emitted from the surface of the Earth as infrared radiation
- However much of the I.R. energy is trapped inside the Earth's atmosphere by Greenhouse gases which can absorb and hold the radiation
- Two such gases are carbon dioxide and methane
- Levels of carbon dioxide and methane in our atmosphere are increasing as a result of human activity
Carbon dioxide
- Sources: combustion of wood and fossil fuels, respiration of plants and animals, thermal decomposition of carbonate rocks and the effect of acids on carbonates
- Main reason for increasing levels: combustion of fossil fuels increasing to meet our demands
Methane
- Sources: digestive processes of animals, decomposition of vegetation, bacterial action in swamps, rice paddy fields and landfill sites
- Main reasons for increasing levels: increase in animal farming, number of paddy fields and landfill sites
The green house effect
- Caused by the presence of greenhouse gases within our atmosphere, mainly methane and carbon dioxide

EXPLANATION
- The Sun emits rays that enter the Earth’s atmosphere
- The heat is absorbed and re-emitted back from the Earth’s surface
- Some heat is reflected back out into space
- But some heat is absorbed by greenhouse gases such as carbon dioxide and methane and is trapped within the Earth’s atmosphere, keeping the Earth warm
- As the concentration of greenhouse gases in the atmosphere increases due to human activity, more heat is trapped within the Earth's atmosphere causing the Earth’s average temperature to rise (global warming)
\ Consequences of global warming:
- Climate change due to the increase in Earth’s temperature
- Water levels will rise as glaciers melt because of high temperatures, causing flooding in low-lying countries
- Extinction of species due to the destruction of natural habitats
- Migration of species as they will move to areas that are more habitable (no droughts)
- Spread of diseases caused by warmer climate
- Loss of habitat due to climate change (animals that live on glaciers)


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THE CARBON CYCLE
- The carbon cycle describes the movement of carbon between the seas, land and atmosphere
- In the atmosphere, the main source of carbon is carbon dioxide
\ Sources of CO2 in the atmosphere
- Combustion of fossil fuels, e.g: methane: * CH4 + 2O2 → CO2 + H2O
- Respiration: the production of energy in living things. The overall reaction of respiration is represented by the equation: * C6H12O6 + 6O2 → 6CO2 + 6H2O
- Decomposition of limestone * CaCO3 → CaO + CO2
- Reactions of acids with carbonates * CaCO3 + 2HCl → CaCl2 + H2O + CO2
\ Removal of carbon dioxide from the atmosphere
- Photosynthesis: the process of producing glucose and oxygen from carbon dioxide and water in plants in the presence of chlorophyll and light: * 6CO2 + 6H2O → C6H12O6 + 6O2
- Carbon dioxide dissolves in the water in seas and oceans and is removed by shellfish for making their calcium carbonate shells
Balancing the Carbon
- Carbon as carbonate, carbon dioxide or organic carbon compounds is present in the sea, the air and under the Earth
- There is a continuous cycle of these compounds between these sources called the carbon cycle
- There is a constant amount of carbon compounds in the sea, atmosphere and under the Earth
- As long as these are balanced, the amount of carbon dioxide in the atmosphere remains constant
- Scientists are worried that increasing the amounts of fossil fuels burned will increase global warming and unbalance the carbon cycle

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