In-Depth Notes on Water and Seawater Chemistry

The Unique Nature of Water

  • Basis for life on earth
    • Human body consists of approximately 60% water
    • Marine organisms contain about 80% water, with specific examples like jellyfish being 95% water
  • Molecular Composition
    • Water is composed of three molecules:
    • 2 hydrogen atoms (H)
    • 1 oxygen atom (O)

States of Water

  • Water exists in three states:
    • Liquid
    • Solid (ice)
    • Gas (water vapor)

Heat Properties of Water

  • Heat Storage
    • Water temperature changes slowly and holds temperature well
  • Ice Formation
    • Few hydrogen bonds break at low temperatures, causing water to become less dense as it freezes
    • Stabilized hydrogen bonds cause water molecules to be held farther apart, which results in lower density of ice compared to liquid water
  • High Heat of Vaporization
    • At high temperatures, hydrogen bonds can be broken, requiring a significant amount of energy to vaporize water due to the need to break multiple hydrogen bonds

Seawater Composition

  • Major Sources of Salts in Seawater
    1. Rocks on land
    2. Earth's interior
  • Seawater Temperature
    • Varies from -20 to 86°F (-29 to 30°C)
  • Average Ocean Salinity
    • Average salinity is about 35 PSU (Practical Salinity Units)
    • Variations in salinity by location:
    • Red Sea: 40 PSU
    • Baltic Sea: 7 PSU
    • Pacific Ocean: 34.5 PSU
    • Factors affecting salinity include precipitation, evaporation, and freezing

Thermocline

  • The thermocline is a transition layer of water in the ocean characterized by a steeper vertical temperature gradient than that in layers above and below it.