Study Notes on Chemical Bonding
Chemical Bonding
Electrovalent / Ionic Bonding
- Definition: This type of bonding involves the transfer of electrons, typically from a metal to a non-metal.
Characteristics:
- Good Conductors of Electricity: Electrovalent compounds, when dissolved in water or molten, conduct electricity due to the presence of charged ions.
- Crystal Structure: They form crystalline solids with organized structures.
- High Melting and Boiling Points: Electrovalent compounds generally showcase elevated melting and boiling points due to the strong ionic bonds between charged ions.
- Insoluble in Organic Solvents: These compounds typically do not dissolve in organic solvents, but can dissolve in polar solvents like water.
Covalent Bond
- Definition: This bond is characterized by the sharing of electrons between atoms, usually occurring between non-metals.
Characteristics:
- Poor Conductors of Electricity: Covalent compounds do not conduct electricity well because they do not have free ions or charged particles.
- Lower Melting and Boiling Points: Generally, covalent compounds have lower melting and boiling points compared to ionic compounds due to weaker intermolecular forces (Van der Waals forces) compared to ionic bonds.
- Less Ionic Character: Covalent bonds often have lower ionic character than ionic bonds due to the nature of electron sharing.
Coordinate Covalent Bond
- Definition: Also known as a dative bond, this occurs when one atom shares a pair of electrons that originated from a single atom when forming a bond with another atom.
Characteristics:
- This bond involves one atom providing both of the electrons for the shared pair, allowing the bond to form without both atoms having to supply electrons.
Example:
- An example of a coordinate covalent bond is the formation of ammonium ion (NH₄⁺), where a nitrogen atom shares a lone pair of electrons with a hydrogen ion (H⁺) to form a stable compound.