Week 7: Postsynaptic Density, Neuroligins, PSD-95, and Related Proteins

The Postsynaptic Density: Overview

  • The postsynaptic density (PSD) is the postsynaptic specialization at synapses, comprising membrane and cytoplasmic proteins clustered immediately opposite release sites or active zones.

    • It includes ligand-gated ion channels (LGICs\mathrm{LGICs}), anchoring proteins, cytoskeleton components, and regulatory proteins.

    • It is called a "density" because it appears particularly dense in electron microscopy images.

  • PSDs differ according to the type of synapse (excitatory vs inhibitory).

  • Core organizing molecules and CAMs play key roles in signal transmission and structural organization across the synapse.

  • Neuroligins (postsynaptic CAMs) form trans-synaptic interactions with neurexins (presynaptic CAMs), helping couple pre- and post-synaptic specialization.

PSD Organization and Architecture

  • The PSD comprises two main layers:

    • PSD core (superficial): high concentration of PSD-95; oriented so that the N-terminus is near the postsynaptic membrane and the C-terminus extends into the spine; positions PSD-95 to bind neurotransmitter receptors.

    • PSD pallium (deeper layer): scaffold of Shank and Homer proteins; becomes denser during intense synaptic activity due to reversible recruitment of CaMKII and other proteins.

  • The pallium thickens with activity, acting as a dynamic signaling scaffold.

  • In excitatory synapses, the PSD contains hundreds to thousands of proteins; in inhibitory synapses, there are substantial but fewer proteins (see alphabet soup below).

The Alphabet Soup of PSD Proteins

  • Excitatory synapses probably have more than >1000 different proteins.

  • Inhibitory synapses have at least 250\ge 250 different proteins.

  • Many PSD proteins are CAMs, so their names do not always reflect function (examples: Homer, Shank, PSD-95, PSD-93, gephyrin).

  • The large diversity underpins the complexity of synaptic signaling and plasticity.

Major Protein Families in the PSD

  • MAGUKs (membrane-associated guanylate kinases):

    • PSD-95 (DLG4, SAP90) is the most abundant MAGUK at the mammalian PSD.

    • Other MAGUKs include SAP97 (DLG1), PSD-93 (DLG2, Chapsyn-110), and SAP102 (DLG3).

  • GKAP (guanylate kinase-associated protein): also called PSD-95-associated protein or DAP-1; binds to Shank and PSD-95.

  • Shank family: also called ProSAP (Proline-rich synapse-associated protein); other names include Synamon and CortBP; SH3-containing and multiple ankyrin-repeat domain proteins; links to the actin cytoskeleton and other scaffolds.

  • Homer family: also called Vesl, Cupidin, PSD-Zip45; links Shank to metabotropic glutamate receptors and IP3 receptors on the smooth endoplasmic reticulum (SER).

PSD as a Signaling Hub

  • PSD proteins are not just structural scaffolds; they organize and propagate signaling cascades, including:

    • NMDA receptors and AMPA receptors (glutamate receptors) anchored within the PSD.

    • Tyrosine kinase receptors (RTKs) and various intracellular signal-transduction molecules.

    • Calcium/calmodulin-dependent protein kinase II (CaMKII), a central signaling node that autophosphorylates and acts as a molecular memory device important for long-term potentiation (LTP).

  • The PSD hosts a wide array of signaling interactions, enabling rapid and coordinated synaptic responses.

Neuroligins, Neurexins, and Trans-synaptic Organization

  • Neuroligins are type I postsynaptic membrane proteins that act as adhesion molecules and ligands for presynaptic neurexins, thereby linking the two sides of the synapse.

  • Neurexins (NRXN) are presynaptic CAMs with a single transmembrane domain and roles in connecting neurons at the synapse.

  • Neuroligins organize the PSD by binding across the synaptic cleft to neurexins, helping to specify synaptic type and maintain synapse structure.

  • Types of Neuroligins:

    • Neuroligin 1 (NLGN1): characteristically found in all glutamatergic synapses.

    • Neuroligin 2 (NLGN2): preferentially at certain inhibitory (GABAergic) synapses.

    • Neuroligin 3 (NLGN3): found in both excitatory and inhibitory synapses.

    • Neuroligin 4 (NLGN4): preferentially at glycinergic synapses in the retina.

  • Neuroligins bind to PSD-95 via the 3rd PDZ domain; PSD-95 binds AMPA receptors via the 1st PDZ domain, helping to stabilize AMPA receptors at the postsynaptic density.

  • The Neuroligin/Neurexin interaction helps anchor AMPA receptors and coordinates synaptic signaling, but other CAMs can also contribute to synapse formation and maintenance.

PSD-95: PDZ Domains and Interaction Network

  • PSD-95 contains 3 PDZ domains (PDZ1, PDZ2, PDZ3) plus SH3 and GK (guanylate kinase) domains.

  • PDZ domains are ~809080{-}90 amino acids in length.

  • Neuroligins bind to PSD-95 via the 3rd PDZ domain; PSD-95 binds AMPA receptors via the 1st PDZ domain; this arrangement helps stabilize AMPA receptors at the synapse.

  • PSD-95 also binds NMDA receptors via PDZ interactions and can associate with CaMKII and neuronal nitric oxide synthase (nNOS), integrating excitatory signaling and plasticity.

  • PSD-95 interacts with several other proteins, including GKAP (to connect to Shank) and Homer, forming a dense signaling network at the PSD's superficial layer.

  • The PSD-95 scaffold thus coordinates receptor anchoring and downstream signaling to shape synaptic strength.

Beyond PDZ: Other Domains of PSD-95 and Interacting Partners

  • PSD-95 has additional domains (SH3 and GUK) that mediate interactions with other partners such as:

    • NRXN1B (neurexin 1B)

    • NLGN1 (neuroligin 1)

    • Additional partners through PDZ-independent interactions.

  • The PDZ-based interactions and SH3/GUK-mediated associations together organize excitatory synapses and organize a network of signaling across the PSD.

Signaling Molecules in the PSD

  • NMDA receptors: critical for calcium influx and synaptic plasticity.

  • CaMKII: autophosphorylates, acts as a molecular memory device, essential for LTP.

  • Neuronal nitric oxide synthase (nNOS): implicated in synaptic plasticity and neuroprotection.

  • Shank proteins: connect to GKAP and, via Homer, to metabotropic glutamate receptors (mGluRs) and IP3 receptors on the SER, enabling Ca2+ signaling from internal stores.

  • The interplay between NMDA receptors, CaMKII, Shank, and Homer governs calcium signaling, receptor trafficking, and plasticity.

Shank, GKAP, and Homer: Structural Coupling and Signaling Bridges

  • Shank proteins couple to the actin cytoskeleton via interactions with GKAP and PSD-95; they act as a bridge from the core PSD to signaling receptors.

  • Shank proteins can bind directly to neuroligins, contributing to trans-synaptic signaling and possibly coordinating presynaptic changes through neurexins.

  • GKAP (DAP-1) binds to Shank and PSD-95, linking the core scaffolds to the larger pallial scaffold.

  • Homer connects Shank to IP3 receptors and thus to intracellular Ca2+ signaling, providing a route from surface receptors to internal Ca2+ stores.

  • The combined Shank–GKAP–Homer network underpins a versatile scaffold for receptor organization and signaling.

Inhibitory Synapses: Gephyrin and GABA/Glycine Clusters

  • In inhibitory synapses, gephyrin is the key organizing molecule.

    • Gephyrin self-assembles into a hexagonal lattice and interacts with various inhibitory postsynaptic density proteins.

    • GABA and glycine receptors (both pentameric transmembrane receptor families) cluster at inhibitory synapses via gephyrin.

  • These receptors are part of the same superfamily as nicotinic acetylcholine receptors (pentameric transmembrane proteins with at least two α-subunits).

  • A key question remains whether nicotinic synapses have PSDs analogous to excitatory PSDs or inhibitory PSDs, highlighting ongoing research gaps in PSD organization across synapse types.

Trans-synaptic Regulation of Presynaptic Specializations

  • Post-synaptic specializations regulate pre-synaptic specializations via CAMs, establishing trans-synaptic coherence.

  • The major example is the neurexin–neuroligin interaction, which links pre- and post-synaptic machinery.

  • Deletion of neuroligin does not completely prevent synapse formation; other cell adhesion molecules can substitute and preserve synapse formation, indicating redundancy in synaptic assembly.

Post-synaptic Density: Composition and Core Functions

  • PSDs include dozens of signal transduction molecules, such as:

    • Glutamate receptors (NMDA-R, mGluR)

    • Tyrosine kinase receptors (RTKs)

    • Many intracellular signaling molecules, notably CaMKII (autophosphorylation supports LTP)

  • The PSD acts as a hub for converting receptor activity into intracellular signaling and reorganizing presynaptic elements.

Summary of Key Points

  • Neuroligins on the postsynaptic membrane bind to presynaptic neurexins, organizing synapse formation and maintenance.

  • There are four neuroligin types with distinct synaptic localizations: NLGN1 (glutamatergic), NLGN2 (inhibitory), NLGN3 (excitatory and inhibitory), NLGN4 (glycinergic retina).

  • PSD-95 (DLG4) is the major MAGUK scaffold in the PSD, containing 3 PDZ domains (PDZ1-3) plus SH3 and GUK domains, and binds multiple partners including NMDA receptors, AMPA receptors, neuroligins, CaMKII, and nNOS.

  • The PDZ domains organize receptor anchoring and signal transduction; Neuroligins bind via the 3rd PDZ domain, while AMPA receptors bind via the 1st PDZ domain of PSD-95.

  • The PSD core (high PSD-95) and pallium (Shank/Homer scaffolds) coordinate receptor organization and signaling; pallium density increases with intense activity due to CaMKII recruitment.

  • Shank, GKAP, and Homer form a critical signaling scaffold linking surface receptors to intracellular Ca2+ signaling through IP3 receptors and actin cytoskeleton interactions.

  • Inhibitory synapses rely on gephyrin to organize GABA and glycine receptor clusters, with gephyrin forming a lattice structure at these synapses.

  • Trans-synaptic CAMs (neurexin–neuroligin and related molecules) coordinate presynaptic active zones with postsynaptic densities; however, disruption of specific CAMs can be compensated by other CAMs, indicating redundancy in synapse formation.

  • The PSD functions as a central signaling hub with components like NMDA receptors, CaMKII, nNOS, and RTKs, underpinning synaptic plasticity, memory formation, and neuroprotection.

  • Autism-linked mutations frequently affect PSD proteins and CAMs, underscoring the importance of PSD organization for normal synaptic function and neurodevelopment.

References to specific slide details (for exam familiarity):

  • PSD layers: core vs pallium; CaMKII-dependent densification during activity.

  • Alphabet soup: excitatory >>1000 proteins; inhibitory >250\ge 250 proteins; examples include Homer, Shank, PSD-95, PSD-93, gephyrin.

  • MAGUKs and GKAP/DAP-1 as scaffolding connectors between Shank and PSD-95.

  • Neuroligins (NLGN1-4) and Neurexins (NRXN) as central trans-synaptic organizers.

  • PDZ-domain architecture of PSD-95 and implications for receptor anchoring and signaling.

  • Shank–Homer–mGluR–IP3 receptor signaling axis and its link to intracellular Ca2+ stores.

  • Gephyrin as the organizing molecule for inhibitory synapses and its lattice-like assembly.