soil fertility

nitrogen

  • nitrogen is a critical component of proteins (and enzymes) nucleic acids, and chlorophyll

  • plants with N deficiency exhibit chlorosis

    • yellow or light green leaves

    • stunted growth

    • thin, spindly leaves

  • plants take up N as;

    • Nitrate (NO3-)

    • Ammonium (NH4+)

    • Dissolved organic N (DON)

rhyzobia

  • rhyzobia form a symbiotic relationship with legumes

  • nitrogen is fixed by the nitrogen generating enzyme nitrogenase

  • ammonia can be used by the plant for its life cycle

  • when the plant dies, the ammonia is released into the soil.

haber-bosch process

  • reaction of nitrogen and hydrogen with a metal catalyst to create ammonia

  • N2 + 3 H2 → 2 NH3

  • energy intensive

  • price of N is usually in lock-step with energy prices

organic forms of N
  • manures

  • green manures

  • composts

  • wood chips

  • anything with a lot of carbon

volitilization
  • high in soils with a low CEC bc NH4 is not fixed within the clay

  • more pronounced at a high pH