Quizlet

Thermodynamics Overview

  • Definition: Study of energy in the form of heat and work, and the fluids used to convert heat to work.

  • Energy Forms:

    • Most abundant form: Heat

    • Most useful form: Work

  • Essential Component for Conversion: Fluid is required for converting heat to useful work.

  • Applications of Thermodynamics: Electrical wiring is not included as an application of thermodynamics.

Fundamental Laws and History

  • First Law of Thermodynamics: Related to the principle of conservation of energy.

  • Pioneer of Thermodynamics: William Rankine authored the first thermodynamics textbook.

  • Energy Quality Determinant: Controlled by Temperature.

SI and English Units

  • Basic Unit of Mass in SI Units: Kilogram (kg).

  • Basic Temperature Unit in SI: Kelvin (K).

  • Basic Mass Unit in English Units: Pound mass (lbm).

  • Basic Temperature Unit in English Units: Degree Rankine (°R).

  • Pressure Conversion: 170 psi = 1,172.1 kPa.

  • Density Calculation: Density of liquid in a tank with mass 12,000 kg and volume 15 m³ is 800 kg/m³.

  • Weight Calculation: Weight (W) of a 200 lbm person at g=32.174 ft/s² is 200 lbf.

Thermodynamic Systems

  • Definition: A thermodynamic system is a quantity of matter or a region in space set aside for study.

  • Open System: A system where mass can cross its boundaries; also known as a control volume.

    • Example: A water heater that allows water to enter, be heated, and leave.

  • System Boundaries: Can be either fixed or movable (True).

Thermodynamic Properties

  • Definition of Property: Characteristic to describe the condition or state of a system.

    • Examples: Pressure, temperature, density.

  • Intensive Properties: Do not depend on mass or size of the system.

    • Examples: Temperature, density, pressure.

    • Common Representation: Lowercase letters for intensive properties except for P and T.

  • Extensive Properties: Depend on mass or size of the system.

    • Examples: Volume, mass, area.

    • Common Representation: Uppercase letters for extensive properties.

Density and Specific Volume

  • Density Equation: ρ = m/V (where m is mass and V is volume).

  • Specific Volume of a Gas: For density 2.85 kg/m³, specific volume is 0.351 m³/kg.

State of a System

  • Definition of State: Condition of the system at a specific time.

  • Equilibrium: A system is in equilibrium if properties do not change when isolated from surroundings.

  • State Principle: Two independent intensive properties are needed to describe a simple compressible system.

  • Work Modes: For a system with two possible work modes, a total of three independent intensive properties are needed.

  • Thermodynamic Process: The state of the system changes from one equilibrium state to another.

Steady and Uniform States

  • Steady State: Properties at a point do not change with time.

  • Uniform State: Properties are the same throughout the system at a given time (False if stated otherwise).

  • If Uniform State is Given: It indicates properties do not change from point to point at a specific time.

Types of Thermodynamic Processes

  • Isothermal Process: Example - System at T1=500 °C and P1=200 kPa to T2=500 °C and P2=700 kPa.

  • Isobaric Process: Example - System at T1=790 °C and P1=2000 kPa to T2=500 °C and P2=2000 kPa.

  • Isochoric Process: Example - System at T1=790 °C and specific volume v1=10 m³/kg to T2=500 °C and v2=10 m³/kg.

  • Cyclic Process: Example - System remains at T1=900 °C and P1=800 kPa to T2=900 °C and P2=800 kPa.