paint- 2020

Field Study Overview

  • Title: Field Study on the Improvement of Indoor Air Quality with Toluene Adsorption Finishing Materials in an Urban Residential Apartment.

  • Authors: Jisoo Jeon, Ji Hun Park, Seunghwan Wi, Beom Yeol Yun, Taeyeon Kim, Sumin Kim.

  • Affiliation: Department of Architecture and Architectural Engineering, Yonsei University, Seoul, South Korea.

  • History: Received on November 29, 2019; revised on February 4, 2020; accepted on February 4, 2020; available online from February 7, 2020.

  • Keywords: Toluene adsorptive paint, indoor air quality, volatile organic compounds (VOCs), activated carbon.

Introduction

  • Context: To address indoor air quality issues in Korean apartments due to VOC emissions from wallpaper and adhesives.

  • Objective: To test the efficiency of toluene adsorptive paint made with activated carbon to reduce toluene concentration in indoor environments.

  • Method: The paint is created by blending activated carbon with an inorganic binder, with tests done on its adsorption performance.

Volatile Organic Compounds (VOCs)

  • Definition: Organic compounds with a boiling point lower than 250°C that easily evaporate at room temperature.

  • Symptoms of Exposure: Include conjunctival irritation, headaches, allergic reactions, and are associated with sick building syndrome.

  • Sources of VOCs: Emitted from burning processes and many household items like paints, adhesives, furniture, and cleaning products.

  • Indoor Concentration: Tends to be higher than outdoors; people spend about 90% of their time indoors, raising concern for health risks.

  • VOCs from Building Materials: Recognized as a significant cause of deteriorating indoor air quality.

  • Removal Techniques: Recovery (adsorption, condensation) and destruction methods (incineration, photocatalysis).

Toluene Adsorptive Paint

  • Composition: Made by mixing activated carbon and inorganic binder.

  • Activated Carbon: Known for high adsorption capacity, resistance to acids/bases, and thermal stability.

  • Research Gap: Limited studies on using activated carbon in paint, contrasting other applications in building materials.

Study Methodology

Materials

  • Activated Carbon: Sourced from Daewon Trading Company; characterized by high surface area, pore volume, and pore diameter.

  • Inorganic Binder Components: Mostly silicates from Pium Innovation Co.

  • Substrates for Testing: Gypsum board, mortar, and glass plate.

Manufacturing of Toluene Adsorptive Paint

  • Preparation Process: Mixed at a 1:2 ratio and applied to substrates using brushes, dried at 80°C, achieving a thickness of 0.5mm.

Experimental Design

Static Experiment
  • Setup: Conducted in a 10L stainless steel chamber with controlled temperature and humidity to determine the adsorption efficiency.

  • Calculation: Adsorption ratio calculated using residual toluene concentration measurements.

Verification Experiment
  • Real-World Application: Conducted in an apartment case study, comparing different application scenarios of the adsorptive paint and wallpaper.

  • Measurement Technique: Indoor toluene concentration monitored over several days post-application.

  • Results: Paint demonstrated significant reduction in indoor toluene levels, confirming its effectiveness.

Results and Discussion

  • Adsorption Performance: High efficiency with average toluene adsorption ranging from 97.9% to 99.1% based on substrate types.

  • Field Experiment Outcomes: Best performance noted with a reduction of up to 96.3% in toluene concentration after usage.

  • Surface Morphology: FE-SEM analysis showed effective pore structures in both activated carbon and painted surfaces aiding in adsorption mechanisms.

  • Chemical Properties: FTIR analysis suggested retention of non-polar functional groups crucial for effective adsorption.

Conclusion

  • Effectiveness: Toluene adsorptive paint significantly improves indoor air quality by absorbing VOCs like toluene from adhesive sources.

  • Practical Implications: Simple application methods coupled with aesthetic options like wallpapers make it a viable choice for residential settings.

  • Broader Usage Potential: Could benefit from wider adoption in construction, especially in places with known VOC emission sources.

Acknowledgements

  • Funding: Research supported by a grant from the Ministry of Land, Infrastructure and Transport, South Korea.