Concise Summary of Lipids
LIPIDS
- Biological molecules, insoluble in water, soluble in nonpolar solvents.
- Composed of waxy, greasy, or oily compounds in plants and animals.
- Functions: energy storage, structural components (cell membranes), insulation.
Types of Lipids
- Saponifiable Lipids: Contain esters, can undergo saponification (e.g., triglycerides, phosphoglycerides).
- Nonsaponifiable Lipids: Do not contain esters, cannot be saponified (e.g., steroids).
Fatty Acids
- Long-chain carboxylic acids ($RCOOH$).
- Nonpolar tails (hydrophobic) and polar heads (hydrophilic).
- Characteristics: straight chains; 10-20 carbons; even carbon number; can be saturated or unsaturated.
Saturated vs Unsaturated Fatty Acids
- Saturated: solid at room temperature (e.g., animal fats).
- Unsaturated: liquid at room temperature (e.g., vegetable oils).
- Unsaturated fats contain cis-double bonds, creating kinks in the chain, affecting packing and melting points.
Triglycerides
- Composed of three fatty acids and glycerol.
- Fats: solids at room temp (mostly saturated).
- Oils: liquids at room temp (mostly unsaturated).
Soaps
- Formed through saponification of triglycerides with strong bases; contain hydrophobic tails and hydrophilic heads, forming micelles.
Phosphoglycerides
- Major components of cell membranes; contain phosphate groups and can be emulsifying agents (e.g., lecithins).
Steroids
- Composed of fused rings; cholesterol is a key component, precursor to bile salts, sex hormones, glucocorticoids.
Prostaglandins
- Involved in numerous body processes, including inflammation and reproduction; inhibited by NSAIDs like aspirin.