IH Particuate discussion 2/23/2026

Particle Size and Suspension

  • Definition of Particle Size

    • Particles wider than 100 microns often drop quickly and do not remain airborne.

    • Example: Wood dust blown from a table with compressed air; some stays airborne temporarily but most drops to the ground.

  • Importance of 100 Microns Cut-off

    • Particles larger than 100 microns tend to settle out and are not classified as airborne particles.

  • Range of Particulate Sizes

    • Size spectrum ranges from 1 nanometer to 1000 microns.

    • Examples of specific particles:

      • 1000 microns: Rain droplets, beach sand.

      • 100 nanometers ( e.g. Zika virus at 45 nanometers)

      • 0.1 to 0.5 microns (e.g. Coronaviruses vary in size).

      • Particulates include: Plant spores, human hair, bacteria, tobacco smoke, coal dust.

Classification of Particulates

  • Categories of Particulates

    • Gases and vapors: less than 1 nanometer.

    • Mists and vapors produced in processes such as painting or plating.

    • Paint mist: mixture of solids and liquids when coating.

  • Example of a Mist

    • Chrome plating dip tank: includes agitation and heat that produces mist.

  • Welding Fumes

    • Defined as a classic example of fumes with recognized carcinogenic properties (Classified by IARC).

    • Terms to know:

    • Welding plume: Visible fume created during welding or cutting processes.

Types of Particulates and Their Environmental Effects

  • Differences Between Mist and Fog

    • Mist does not linger like fog does; fog represents finer particles.

  • Routes of Entry for Chemicals

    • Primary routes: Inhalation, absorption, and ingestion.

    • Hexavalent chromium noted as a dermal sensitizer.

  • Environmental and Health Regulations

    • OSHA PNOR: Particles Not Otherwise Regulated, specified limits for total (
      15extmg/m315 ext{ mg/m}^3) and respirable particles (5extmg/m35 ext{ mg/m}^3).

    • ACGIH terms: PNOS (Particles Not Otherwise Specified) with inhalable (10 mg/m³) and respirable versions (3 mg/m³).

Measurement and Sampling Techniques

  • Determining Exposure

    • Used for particulates lacking specific exposure standards.

    • Examples: Drywall dust or wood dust that doesn't have specific limits.

  • Understanding Particulate Size

    • Exposure limits defined under specific sampling methods:

    • Total, inhalable, thoracic, and respirable definitions based on size in microns.

      • Total: <100 ext{ microns}.

      • Inhalable: <10 ext{ microns}.

      • Thoracic: <4 ext{ microns}.

      • Respirable: Particles that penetrate the respiratory system.

  • Sampling Technology

    • Old standard cassette often samples inaccurately for particles larger than 30 microns, leading to misrepresentation of exposure data.

    • Newer technology (parallel particle impactor) captures particles more accurately based on size and flow.

Significant Health Considerations

  • Pneumoconiosis

    • General term for dust accumulation in lungs which can be reversible, stable, or progressive based on exposure ceasing or continuing.

  • Particle Deposition Mechanisms

    • Sedimentation: Heavy particles fall out of suspension due to gravity.

    • Inertial impaction: Particles collide with surfaces due to their velocity.

    • Diffusion or Brownian motion: Light particles exhibit random movement affected by currents.

    • Interception: Particles get caught in small spaces or gaps.

    • Electrostatic: Charged particles attracted to opposite charges.

    • Centrifugal action: Liabilities in cyclone samplers to separate heavier particles from lighter ones.

    • Thermal movement (phoretic): Gas or vapor movement based on temperature gradients.

Sampling Techniques for Airborne Particulates

  • Personal Breathing Zone (PBZ): Sampling typically done within a 9-inch radius around the mouth and nose of a worker.

  • Real-Time vs Integrated Sampling

    • Real-time allows for immediate exposure assessment but is limited in detail (does not specify particle type).

    • Integrated sampling provides average exposure data over time but requires laboratory analysis for identification.

  • Surface Sampling

    • Wipe samples used to assess surface contamination potential in operations, such as areas where respiratory sensitizers are expected.

Specific Case Studies and Procedures

  • Sodium Bisulfite Exposure Incident

    • Exposure levels verified through air sampling in a wastewater treatment context; sensitivity issues explored.

    • OELs established at 5extmg/m35 ext{ mg/m}^3.

  • Surface Sampling Procedure

    • Surfaces sampled using wipes, ensuring that cross-contamination is avoided.

    • Results interpreted based on specific surface limits where contamination might indicate violations of safety standards.

  • Current Sampling Practices and Technology

    • Highlighting the importance of using the latest sampling technology to ensure accurate assessments of both particulate and gaseous exposures in occupational settings.