Half-Life Notes
Half-Life
- Definition: The time it takes for half of the atoms in a radioactive sample to decay.
Visual Representation of Decay
- Imagine radioactive elements as black dots that decay into red dots.
- Beginning: 100% black dots (radioactive element).
- After One Half-Life:
- 50% black dots, 50% red dots. If you started with 20 black dots, you'd have 10 black and 10 red.
- After Another Half-Life:
- 25% black dots, 75% red dots. Starting from the previous state (10 black, 10 red), you'd have 5 black and 15 red.
Factors Independent of Half-Life
- Half-life is independent of:
- Temperature
- Pressure
- Concentration
Half-Life Uniqueness
- Each radioisotope has its own unique half-life.
- Some are very long (billions of years).
- Some are very short (microseconds).
Example: Uranium-238
- Half-life of Uranium-238 is approximately 4.47 \text{ billion years}. This is useful for approximating the age of the Earth.
Formulas for Half-Life Calculations
- n = Number of half-lives
- Fraction Remaining: \frac{1}{2}^n
- Mass Remaining = (Original Mass) * (Fraction Remaining)
Sample Problem: Radium-222
Problem: How long will it take for 30 grams of Rn (Radium) -222 to decay to 7.5 grams?
Set up a T-chart to track mass vs time.
Identify what you are looking for (time elapsed) and what is given (initial and final masses).
Solution:
- Original mass: 30 grams at time 0.
- After 1 half-life: 15 grams.
- After 2 half-lives: 7.5 grams.
Find the half-life of Rn-222 from Table N: 3.823 \text{ days}.
Time elapsed to reach 7.5 grams = 2 * (half-life) = 2 * 3.823 = 7.646 \text{ days}.
Sample Problem: N-16
- Problem: How many grams of N-16 will be left on a 60 gram sample after 21.6 seconds?
- Set up a T-chart to track mass vs time
- Initial time: 0 seconds. Initial mass: 60 grams
- From Table N, the half-life of N-16 is 7.13 seconds.
- After one half-life (7.13 seconds): 30 grams
- After two half-lives (14.26 seconds): 15 grams
- After three half-lives (21.39 seconds): 7.5 grams
- The presenters solve it a second time for verification
- The final answer is 7.5 grams
Sample problem: Determining Fraction Remaining and Time
- Problem: What fraction of a sample will be left after 42.9 days, and how long is three half lives?
- Identify the knowns and unknowns.
- After one half life is 14.28 days.
- After two half lives 28.56 days.
- After three half lives is 42.84 days.
- Fraction remaining is calculated as the third power of one half (1/2), or (1/2)^3.
- Find the half life for O^{15}, which is 1.599 s
- Multiple 1.599 by three for the final answer (4.07).