Chemical Reactions and Changes

Types of Change

  • Physical Change: A change that does not affect the identity of a substance; no chemical bonds are broken or formed. Examples include phase changes of water (H2OH_2O) such as boiling, freezing, or melting.
  • Chemical Change: A change where the identity of the substances involved changes because chemical bonds are broken and/or formed. An example is the reaction of sodium (NaNa) and chlorine (Cl2Cl_2) to form sodium chloride (NaClNaCl).
  • Chemical Reaction: The process by which chemical change occurs, resulting in the transformation of one or more substances into different substances.

Indicators of Chemical Change

  • Color Change: Examples include iron turning into rust or clear air turning into brownish smog.
  • Smell Change: Examples include milk turning sour or wine smelling like vinegar.
  • Energy Change:
    • Exothermic Reaction: A reaction that releases energy, often detectable as an increase in temperature or the emission of light (e.g., a burning candle).
    • Endothermic Reaction: A reaction that absorbs energy, often detectable by a drop in temperature (e.g., mixing vinegar and baking soda) or used in processes like photosynthesis.
  • Gas Release: Indicated by fizzing or bubbling, such as AlkaSeltzerAlka-Seltzer tablets in water.
  • Precipitate Formation: The formation of a solid that separates out of a solution, such as the blue gelatinous copper(II) hydroxide (Cu(OH)2Cu(OH)_2) formed from mixing sodium hydroxide and copper(II) sulfate.

Chemical Equations and Balancing

  • Chemical Equation: A symbolic description of a chemical reaction.
  • Components:
    • Reactants: Original substances on the left side of the equation.
    • Products: New substances formed on the right side of the arrow.
    • State Symbols: (s)(s) for solid, (l)(l) for liquid, (g)(g) for gas, and (aq)(aq) for aqueous solution (dissolved in water).
    • Chemical Coefficient: The number in front of a compound representing the whole-number ratio of reactants and products.
  • Law of Conservation of Mass: Matter is neither created nor destroyed; a balanced equation must have the same number of atoms for each element on both sides of the arrow.
  • Diatomic Elements: Elements that exist naturally in pairs: H2H_2, N2N_2, O2O_2, F2F_2, Cl2Cl_2, Br2Br_2, and I2I_2 (Mnemonic: BrINClHOFBrINClHOF).
  • Catalyst: A substance that speeds up a reaction without being consumed. It is written above the reaction arrow (e.g., KIKI in the decomposition of H2O2H_2O_2).

Environmental Context: Greenhouse Gases and the Carbon Cycle

  • Virgin Earth Challenge: A $25,000,000 award announced by Sir Richard Branson for technology that removes greenhouse gases from the atmosphere for at least 10 years.
  • Greenhouse Gases: Carbon dioxide (CO2CO_2) and methane (CH4CH_4) trap heat near the Earth.
  • Carbon Cycle: The movement of carbon through photosynthesis, combustion, decay, and respiration.
  • Atmospheric Trends:
    • Historical CO2CO_2 levels: 200200 to 300ppm300\,ppm.
    • Recent average concentration: approximately 356ppm356\,ppm, increasing at 1.5ppm1.5\,ppm per year.
    • Global temperature: Increased by 0.5C0.5^{\circ}C in the past century; predicted to rise by 45C4-5^{\circ}C if greenhouse gas levels are not managed.