Chemical Reactions and Changes
Types of Change
- Physical Change: A change that does not affect the identity of a substance; no chemical bonds are broken or formed. Examples include phase changes of water (H2O) such as boiling, freezing, or melting.
- Chemical Change: A change where the identity of the substances involved changes because chemical bonds are broken and/or formed. An example is the reaction of sodium (Na) and chlorine (Cl2) to form sodium chloride (NaCl).
- Chemical Reaction: The process by which chemical change occurs, resulting in the transformation of one or more substances into different substances.
Indicators of Chemical Change
- Color Change: Examples include iron turning into rust or clear air turning into brownish smog.
- Smell Change: Examples include milk turning sour or wine smelling like vinegar.
- Energy Change:
- Exothermic Reaction: A reaction that releases energy, often detectable as an increase in temperature or the emission of light (e.g., a burning candle).
- Endothermic Reaction: A reaction that absorbs energy, often detectable by a drop in temperature (e.g., mixing vinegar and baking soda) or used in processes like photosynthesis.
- Gas Release: Indicated by fizzing or bubbling, such as Alka−Seltzer tablets in water.
- Precipitate Formation: The formation of a solid that separates out of a solution, such as the blue gelatinous copper(II) hydroxide (Cu(OH)2) formed from mixing sodium hydroxide and copper(II) sulfate.
Chemical Equations and Balancing
- Chemical Equation: A symbolic description of a chemical reaction.
- Components:
- Reactants: Original substances on the left side of the equation.
- Products: New substances formed on the right side of the arrow.
- State Symbols: (s) for solid, (l) for liquid, (g) for gas, and (aq) for aqueous solution (dissolved in water).
- Chemical Coefficient: The number in front of a compound representing the whole-number ratio of reactants and products.
- Law of Conservation of Mass: Matter is neither created nor destroyed; a balanced equation must have the same number of atoms for each element on both sides of the arrow.
- Diatomic Elements: Elements that exist naturally in pairs: H2, N2, O2, F2, Cl2, Br2, and I2 (Mnemonic: BrINClHOF).
- Catalyst: A substance that speeds up a reaction without being consumed. It is written above the reaction arrow (e.g., KI in the decomposition of H2O2).
Environmental Context: Greenhouse Gases and the Carbon Cycle
- Virgin Earth Challenge: A $25,000,000 award announced by Sir Richard Branson for technology that removes greenhouse gases from the atmosphere for at least 10 years.
- Greenhouse Gases: Carbon dioxide (CO2) and methane (CH4) trap heat near the Earth.
- Carbon Cycle: The movement of carbon through photosynthesis, combustion, decay, and respiration.
- Atmospheric Trends:
- Historical CO2 levels: 200 to 300ppm.
- Recent average concentration: approximately 356ppm, increasing at 1.5ppm per year.
- Global temperature: Increased by 0.5∘C in the past century; predicted to rise by 4−5∘C if greenhouse gas levels are not managed.