Nuclear Physics - The Atom and Its Components

Nuclear Physics - Week 5: The Atom and Its Components

Learning Outcomes

  • Describe the structure of the atom and its components.

  • List the nuclear families and state their characteristics.

  • Introduce and define the following terms:

    • Mass number

    • Atomic number

    • Neutron number

    • Binding energy

    • Valence state

    • Chart of nuclides

    • Line of stability

    • Proton

    • Neutron

    • Electron

    • Nucleons

    • Electron shells

    • Quantum number

    • Matter

    • Atom

    • Molecule

    • Isotope

    • Isotone

    • Isobar

    • Isomer

Composition of Matter

  • Matter: All matter is comprised of atoms.

  • Atoms: The smallest unit into which a chemical element can be divided without losing its chemical identity.

  • Molecules: Formed when atoms combine together.

  • Examples of Elements:

    • Oxygen (O)

    • Hydrogen (H)

    • Water (H₂O)

Atomic Composition & Structure

  • Atoms are made up of subatomic particles including protons, neutrons, and electrons.

  • Nucleus: The atomic nucleus is made of protons and neutrons, which are collectively known as nucleons.

  • Protons: Positively charged particles found in the nucleus.

  • Neutrons: Neutral particles with a mass slightly greater than that of a proton, also found in the nucleus.

  • Electrons: Negatively charged particles that orbit the nucleus and are considered to have negligible mass.

Bohr’s Atomic Theory

  • Proposed by Niels Bohr in 1913.

    • Protons: +1 charge, mass approximately 1,836 times that of an electron.

    • Neutrons: 0 charge, mass slightly greater than a proton.

    • Electrons: -1 charge, zero mass; exist in definite energy levels or orbits around the nucleus.

Characteristics of Subatomic Particles

Particle

Charge

Mass (amu)

Mass/Energy (MeV)

Location in Atom

Proton

+1

1.007276

938.272

Nucleus

Neutron

0

1.008665

939.565

Nucleus

Electron

-1

0.000549

0.511

Extranuclear

Fun Facts About Atoms

  • Atoms are mainly composed of empty space, with over 99.9% of the mass located in the nucleus.

  • The nuclear force refers to the force that holds nucleons together in the nucleus.

Neutron Properties

  • Neutrons are unstable outside of the nucleus and will convert into a proton and an electron in approximately 17 minutes.

  • Neutrons are stable within the nucleus unless they undergo radioactive decay.

Electrons

  • In a stable atom, the number of electrons equals the number of protons.

  • Electrons reside in stable orbits or shells within the atom where they can exist indefinitely without losing energy.

Quantum Numbers and Electron Shells

  • The diameters of the electron shells are determined by quantum numbers (n):

    • K-shell: n = 1

    • L-shell: n = 2

    • M-shell: n = 3

    • N-shell: n = 4

  • The maximum number of electrons that can occupy each shell is given by the formula: 2n22n^2.

Electron Orbital Energy and Raw Quantum Mechanics

  • Electrons can transition between orbitals; energy is released as a photon when an electron moves from a higher to a lower energy level.

  • The naming of orbitals corresponds to energy levels, with farther orbitals from the nucleus having higher energy.

Electron Configurations of Elements

  • Example for Technetium (Tc): Electron Shells: 2, 8, 18, 13, 2

  • General configuration representation:

    • 1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹⁰ 4p⁶ 5s² 4d¹⁰

Binding Energies

  • Electrons are held in atoms by electrical forces, with greater binding energies observed in higher atomic number elements.

  • The closer the electron is to the nucleus, the stronger the binding energy.

    • Higher binding energy indicates it requires more energy to remove an electron.

Binding Energy Definitions

  • Negative Binding Energy: Indicates energy needed to liberate the electron from the atom.

Nuclear Nomenclature

  • Nuclide: Any distinct arrangement of protons and neutrons in the nucleus with a measurable lifetime.

  • Isotopes: Nuclides with identical atomic numbers (Z) but differing mass numbers (A).

  • Isotones: Nuclides with the same neutron number but differing mass numbers.

  • Isobars: Nuclides with the same mass number but differing atomic numbers.

  • Isomers: Nuclides that share the same mass number and atomic number, but have different energy states of the nucleus.

Families of Nuclides

  • Isotope Examples: Different isotopes of iodine include I-125, I-127, I-131, where Z remains constant but A varies, affecting physical properties.

  • Example of Isotopes of Hydrogen:

    • Hydrogen-1 (protium): 1p+ 0n

    • Hydrogen-2 (deuterium): 1p+ 1n

    • Hydrogen-3 (tritium): 1p+ 2n

Stability and Decay Modes

  • Line of Stability: Graphical representation of stable vs. radioactive nuclides plotted by neutron number (n) against proton number (p).

  • Primary Decay Modes: Includes various decay processes such as alpha decay, beta decay, and electron capture.

Chart of the Nuclides

  • A chart representing various isotopes alongside their neutron and proton counts, labeling stability and decay type.

Key Terms Recap

  • Nuclide: Combination of protons and neutrons.

  • Isotope: Same Z, different A.

  • Isotone: Same N, different A.

  • Isobar: Same A, different Z.

  • Isomer: Same A and Z, varying nuclear states.