Air Pollution Notes

Air Pollution

  • Air pollution is a global issue because the atmosphe re surrounds the entire planet.

  • Air pollution is defined as the introduction of chemicals, particulate matter, or microorganisms into the atmosphere at concentrations high enough to harm plants , a

  • nimals, and materials or alter ecosystems.

Chemical Pollu tants

  • These pollutants are often released through the combustion of fossil fuels.

  • Sulfur Dioxide (SO2):

    • Sulfur is present in varying amounts in plants and animals, and : consequently, in fossil fuels derived from their remains.

  • Nitrogen Oxides (NOx):

    • Can exist as either nitrogen oxide (colorless, odorless) or nitrogen dioxide (pungent, reddish-brown).

    • These forms can easily transform from one to the other in the atmosphere.

  • Carbon Oxides:

    • Carbon monoxide (CO) is a common emission from vehicle exhaust and other combustion processes.

    • Carbon dioxide (CO2) released by burning fossil fuels has become a major pollutant.

Particulate Matter

  • Defined as solid or liquid particles suspended in the air.

  • Sources include:

    • Combustion of wood, coal, oil, gasoline, etc.

    • Road dust and rock crushing.

    • Volcanoes.

    • Forest fires.

    • Dust storms.

Volatile Organic Compounds (VOCs)

  • A VOC is an organic compound that evaporates at typical atmospheric temperatures and is a precursor to ozone.

  • Many VOCs are hydrocarbons.

  • Formed by the evaporation of fuels, solvents, paints, and the incomplete combustion of fuels like gasoline.

Photochemical Oxidants

  • A class of air pollutants formed as a result of sunlight acting on chemical compounds like nitrogen oxides.

  • Ozone (O3):

    • A type of photochemical oxidant.

    • A secondary pollutant made up of three oxygen atoms bound together.

    • Can be beneficial or harmful depending on its location (stratosphere vs. troposphere).

  • In the presence of sulfur and nitrous oxides, photochemical oxidants can worsen smog.

Photochemical Smog

  • Smog is a type of air pollution that is a mixture of oxidants and particulate matter.

  • Two types of smog:

    • Photochemical smog:

      • Dominated by oxidants such as ozone.

      • Also known as Los Angeles-type smog or brown smog.

    • Sulfurous smog:

      • Dominated by sulfur dioxide and sulfate compounds.

      • Also known as London-type smog, gray smog, or industrial smog.

Primary and Secondary Pollutants

  • Primary pollutant:

    • A polluting compound that comes directly from a smokestack, exhaust pipe, or natural emission source.

    • Examples: CO, CO2, SO2, NOx, and most suspended particulate matter.

  • Secondary pollutant:

    • A primary pollutant that has undergone transformation in the presence of sunlight, water, oxygen, or other compounds.

    • Examples: O3, sulfate, and nitrate.

  • The transformation from primary to secondary pollutants requires factors such as sunlight, water (clouds), and appropriate temperatures.

Anthropogenic Emissions

  • Recent EPA data indicates that on-road vehicles (