Nuclear Chemistry Notes

Table O: Symbols Used in Nuclear Chemistry

Overview

  • Radioactive elements emit particles and/or energy from their nuclei.
  • These nuclear particles or energy have different effects on the nuclei of these elements.
  • Radioactive decay process is represented by nuclear equations, showing the identity of the reactants, products, and the radiation released.
  • In these equations, both charge and mass must be conserved.
  • To balance a nuclear equation:
    • The sum of the atomic charge numbers on each side must be equal.
    • The sum of the mass numbers on each side must be equal.

Table of Symbols

  • The table provides the Name, Notation (used in writing nuclear equations), and Symbol of common types of radiation.
  • Going down the chart in order:
    • Alpha particle (\alpha):
      • Helium nucleus and is therefore positively charged.
      • Notation: {}{2}^{4}He or {}{2}^{4}\alpha
    • Beta particle (\beta^-):
      • Ordinary electron and is therefore negatively charged.
      • Notation: {}{-1}^{0}e or {}{-1}^{0}\beta
    • Gamma radiation (\gamma):
      • Emission of pure energy from the nucleus.
      • Carries no charge or mass.
      • Notation: {}_{0}^{0}\gamma
    • Neutron (n):
      • Neutral particle of unit mass found in the nucleus of atoms.
      • Notation: {}_{0}^{1}n
    • Proton (p):
      • Hydrogen nucleus, a positive particle of unit mass found in the nucleus of atoms.
      • Notation: {}{1}^{1}H or {}{1}^{1}p
    • Positron (\beta^+):
      • Positive electron.
      • Notation: {}{+1}^{0}e or {}{+1}^{0}\beta
  • Mass number:
    • The number at the upper left of the notation.
  • Atomic number:
    • The number at the lower left of the notation.
  • When a particle is emitted, conservation of these numbers must take place with the reactants and products.
  • If the emission of the particle affects the atomic number, the identity of the element changes.

Additional Information on Radioactive Decay:

  • Alpha decay/emission:
    • Atomic number decreases by 2.
    • Mass number decreases by 4.
    • Example: {}{88}^{226}Ra \rightarrow {}{86}^{222}Rn + {}_{2}^{4}He
  • Negative beta decay/emission:
    • Atomic number increases by 1.
    • Mass number remains the same.
    • Example: {}{92}^{239}U \rightarrow {}{93}^{239}Np + {}_{-1}^{0}e
  • Gamma emission:
    • Both the atomic number and mass number remain the same.
    • Example: {}{92}^{239}U \rightarrow {}{92}^{239}U + {}_{0}^{0}\gamma
  • Neutron emission:
    • Atomic number remains the same.
    • Mass number decreases by 1.
  • Proton emission:
    • Both the atomic number and mass number decrease by 1.
    • Example: {}{27}^{58}Co \rightarrow {}{26}^{57}Fe + {}_{1}^{1}H
  • Positron emission (positive beta emission):
    • Atomic number decreases by 1.
    • Mass number remains the same.
    • Example: {}{29}^{58}Cu \rightarrow {}{28}^{58}Ni + {}_{+1}^{0}e
  • Natural transmutation:
    • The identity of a nucleus or element changes due to a change in the number of protons (atomic number) in the nucleus.
    • Example: {}{94}^{239}Pu \rightarrow {}{92}^{235}U + {}_{2}^{4}He
  • Artificial transmutation:
    • Occurs when a stable (nonradioactive) nucleus is bombarded with particles, causing it to become radioactive.
    • Example: {}{4}^{9}Be + {}{2}^{4}He \rightarrow {}{6}^{12}C + {}{0}^{1}n
  • Nuclear fusion:
    • Combining of lightweight nuclei to produce a heavier nucleus.
    • Usually involves hydrogen nuclei combining to produce a helium nucleus.
    • This is the source of solar energy.
    • Example: {}{1}^{2}H + {}{1}^{3}H \rightarrow {}_{2}^{4}He + energy
  • Nuclear fission:
    • Splitting of a heavier nucleus into lighter weight nuclei.
    • U-235 and Pu-239 are the most common elements to undergo fission.
    • This is the source of the energy produced in nuclear reactors.
    • Example: {}{92}^{235}U + {}{0}^{1}n \rightarrow {}{54}^{140}Xe + {}{38}^{94}Sr + 2{}_{0}^{1}n + energy
  • Nuclear reactions release large amounts of energy due to the conversion of some mass into energy according to Einstein's equation: E=mc^2
  • Penetrating power of radiation:
    • Alpha radiation: Weakest penetrating power due to being the largest particle.
    • Gamma radiation: Greatest penetrating power due to being massless and neutral.

Table N: Selected Radioisotopes

Overview

  • The nucleus of many elements is unstable and gives off particles and/or energy when going to a more stable state.
  • These elements are called radioactive elements.
  • This process is referred to as radioactive decay, and the emitted particles or energy is referred to as radiation.
  • The term radioisotope is a contraction of the words radioactive isotope.

Table Information

  • Table N lists the Nuclide, Half-Life, Decay Mode, and the Nuclide Name of selected radioisotopes.
  • Nuclide:
    • The symbol and mass number are given for each nuclide.
    • Atomic number can be obtained from the Periodic Table.
    • Nuclide refers to any nucleus.
    • Decay of the radioisotopes occurs in the nucleus.
  • Half-life:
    • The time in which one-half the nuclei of a sample of that radioisotope decays.
  • Decay mode:
    • Indicates what particle is emitted as the nucleus undergoes decay.
    • Decay modes listed on the table:
      • \beta^-: Negative beta decay, which is the emission of an ordinary electron.
      • \beta^+: Positive beta decay, which is the emission of a positive electron or a positron.
      • \alpha: Alpha decay, which is the emission of a particle identical to a helium nucleus.
    • See Table O for Symbol and Notation.

Radioactive Decay

  • During radioactive decay, a radioactive element gradually changes into another element.
  • The time in which one-half of the nuclei of the original element decays is called the half-life.
  • Table N gives the half-lives of selected radioisotopes.
  • Each radioactive isotope has its own half-life that is unaffected by pressure, temperature, or any other external factors.
  • When a substance undergoes radioactive decay, the radiation decreases, but the half-life remains constant.
  • At the conclusion of each half-life, the mass of the radioactive sample is one-half of the mass it had at the beginning of that half-life.

Half-Life Example 1

  • What amount remains of a 20-gram sample of radium-226 after 4,797 years?
  • From Table N, the half-life of radium-226 is 1,599 years.
  • Since the half-life is constant, 4,797 years equals 3 half-lives:
    • \frac{4797 \text{ years}}{1599 \text{ years}} = 3
  • After each half-life, the amount of radioactive isotope remaining would be half of the original amount, or:
    • After the 1st half-life, 10 grams remain.
    • After the 2nd half-life, 5 grams remain.
    • After the 3rd half-life, 2.5 grams remain.
  • Answer: 2.5 g

Half-Life Example 2

  • What fraction remains of a 20-gram sample of radium-226 after 4,797 years?
  • Using the same procedure as Example 1 and including the fractional amounts:
    • After the 1st half-life, 10 grams remain, which is 1/2 of the original amount.
    • After the 2nd half-life, 5 grams remain, which is 1/4 of the original amount.
    • After the 3rd half-life, 2.5 grams remain, which is 1/8 of the original amount.
  • Answer: 1/8

Half-Life Example 3

  • How much time must elapse before 16 grams of potassium-42 decays, leaving 2 grams of potassium-42 radioactive?
  • Table N shows that potassium-42 ({}^{42}K) has a half-life of 12.36 hours.
  • This is the time it takes for half of the radioactive substance to decay.
  • Since the half-life is a constant, the time for the first half-life would be 1 x 12.36 h or 12.36 hours, and the amount remaining would be half of the original, or 8 grams.
  • The time for two half-lives would be 2 x 12.36 h or 24.72 hours, and 4 grams would remain.
  • The time for three half-lives would be 3 x 12.36 h or 37.08 hours, and 2 grams of the original sample would remain radioactive.
  • Answer: 37.08 h

Additional Information

  • In most cases, the identity (name) of the nuclide changes during radioactive decay.
  • Another decay mode not shown on the table is gamma emission (\gamma), which is the emission of pure energy from the nucleus.
  • Radioisotopes are used in dating geologic and archeological finds.
    • C-14, found in all plant and animal matter, is used to date such finds.
    • U-238 is used to date minerals.
  • Radioisotopes with short half-lives, which will be quickly eliminated from the body, are used medicinally.
    • An example is the use of I-131, with a half-life of 8.021 days, to treat thyroid disorders.
  • Other medical uses of radioisotopes:
    • Ra-226 and Co-60 are used in cancer therapy.
    • Tc-99 is used to pinpoint brain tumors.
  • Radiation can be used to kill insect eggs, molds, bacteria, and yeasts in foods, increasing the shelf-life of certain food items.