Final_ Oxygen Consumption
Hemoglobin and Oxygen Transport
Hemoglobin
Respiratory pigment in vertebrates that enhances oxygen-loading capacity of blood.
Oxygen Equilibrium Curve
Represents the percentage of heme bound to oxygen.
Displays a sigmoidal shape due to positive cooperativity.
Can be manipulated by changes in:
CO2 levels
pH
Temperature
2,3-Bisphosphoglycerate (2,3-BDG)
Carbon Dioxide Transport in Blood
CO2 Transport Mechanisms
CO2 is more soluble in plasma than O2, but not very soluble overall.
Approximately 5% of CO2 is transported dissolved in plasma.
CO2 binds to hemoglobin, forming carbaminohemoglobin, accounting for about 20% of transport.
Binding occurs not at heme groups but at amino-terminal groups of protein chains.
Remaining ~75% is converted to bicarbonate in red blood cells before being transported in plasma.
Role of Carbonic Anhydrase
Carbonic Anhydrase
Enzyme that catalyzes the conversion of carbon dioxide and water into carbonic acid.
Follows the law of mass action, where increased CO2 leads to greater bicarbonate and hydrogen ions production.
Gas Exchange Mechanisms
Systematic and Pulmonary Capillaries
Blood flow and partial pressures of CO2 and O2 are crucial in gas exchange.
Systemic capillaries demonstrate PCO2 = 46 mm Hg, while pulmonary capillaries show PCO2 = 40 mm Hg.
Effects of Partial Pressure
Haldane Effect
Influences how blood transports CO2 in conjunction with O2 loading/unloading related to partial pressures of O2 (PO2) and CO2 (PCO2).
Thermodynamics in Metabolism
2nd Law of Thermodynamics
Describes how energy transformations increase disorder within isolated systems.
External energy sources are needed to maintain internal order within organisms.
Forms of Energy and Work in Animals
Energy Types
Animals utilize:
Chemical Energy from covalent bonds.
Electrical Energy from voltage across membranes.
Mechanical Energy from body motion.
Energy is spent on:
Cellular Work (metabolism, homeostasis)
Mechanical Motion
Heat (random motion, not work-capable)
Metabolic Rate Overview
Metabolic Rate Definition
Rate of converting chemical energy to heat and work, significantly dominated by heat generation.
Dictates food intake for maintenance and impact on ecosystems.
Types of Metabolic Rate
Basal Metabolic Rate (BMR): Measured in homeothermic animals under stress-free conditions.
Standard Metabolic Rate (SMR): Measured in poikilothermic animals under similar conditions.
Maximum Metabolic Rate (MMR): Highest oxygen consumption rate an organism can achieve.
Measuring Metabolic Rate
Direct Calorimetry
Measures heat loss from an organism at rest and during activity.
Indirect Calorimetry (Respirometry)
Infers metabolic rate from oxygen consumption and carbon dioxide production!
Simplified equation: C6H12O6 + 6O2 → 6CO2 + 6H2O + 2820 kJ/mol.
Factors Affecting Metabolic Rate
Major Factors:
Physical activity intensity and ambient temperature.
Other factors include:
Ingestion of food
Age
Gender
Time of day
Specific Dynamic Action (SDA)
SDA refers to the increase in metabolic rate post-ingestion due to energy expenditure in digestion and absorption.
Allometric Scaling of Metabolic Relationships
Allometric Equation
Y = aMb,
Where Y is a biological variable, M is body size, and a & b are constants.
Example of Allometric Scaling
A 30g vole consumes ~175g of food per week (~600% of body weight).
A 1900kg rhino consumes ~650kg of food per week (~34% of body weight).
Metabolic Scaling
Energy needs in homeothermic animals don’t linearly correlate with body size, showing a negative allometric relationship.