Science 10 Chemistry: The Periodic Table, Energy Level Diagrams, and Ions

  • The Periodic Table: History and Organization

  • Mendeleev's Contribution

    • Dmitri Mendeleev organized elements according to recurring or "periodic" properties.

    • He utilized a system that left gaps for elements that were "missing" or yet to be discovered at the time.

    • Prior versions of the periodic table were organized based on atomic weights.

    • Mendeleev arranged elements according to their atomic number (atomic #\text{atomic \#}).

    • Instruction noted in the text: "Do Not Copy".

  • Early Attempts and Specialized Groupings

    • Early versions of the Periodic Table featured different layouts, including identified groups for:

      • Superactinides: Elements beyond the standard actinide series.

      • Transition Metals: Located in the central block of the table.

      • Lanthanides & Actinides: Positioned at the bottom of the table to maintain organizational flow.

Periods and Rows

  • Definition: Periods are the horizontal rows that run across the periodic table.

  • Labeling: There are 77 primary periods labeled from top to bottom.

  • Function: The period number represents the total number of electron shells (energy levels) present in the atoms of those elements.

  • Specific Elements Mentioned in Rows:

    • Period 1: Hydrogen (HH, 1.011.01) and Helium (HeHe, 4.004.00).

    • Period 2: Lithium (LiLi, 6.946.94), Beryllium (BeBe, 9.019.01), Boron (BB, 10.8110.81), Carbon (CC, 12.0112.01), Nitrogen (NN, 14.0114.01), Oxygen (OO, 16.0016.00), Fluorine (FF, 19.0019.00), and Neon (NeNe, 20.1820.18).

Groups and Families

  • Definition: Groups or Families are the vertical columns that run down the periodic table.

  • Labeling: These are labeled from 11 to 1818.

  • Significance:

    • A family may consist of one single column or several columns grouped together.

    • Elements within the same group share similar chemical properties.

    • The group number determines the number of valence electrons (electrons in the outer shell).

  • Named Groups and Specific Properties:

    • Alkali Metals: Group 11. These are soft metals that react very easily with H2OH_2O to form a base (alkali).

    • Alkaline Earth Metals: Group 22. These are light, reactive metals that form oxide coatings.

    • Halogens: Group 1717. These elements react with metals to form "salts."

    • Noble Gases: Group 1818. These are unreactive or "inert" gases.

    • Transition Elements: Groups 33 through 1212. These exhibit a wide range of physical and chemical properties.

    • Lanthanides: Atomic numbers 5858 to 7171.

    • Actinides: Atomic numbers 9090 to 103103. These are mostly radioactive or synthetically produced.

    • Rare Earth Elements: A collective term for the Lanthanides and Actinides.

    • Transuranic Elements: These are the synthetic elements found beyond Uranium (UU) on the periodic table.

Classification of Elements and the Staircase Line

  • The "Staircase" Line:

    • This line acts as a boundary separating metals from non-metals.

    • Metalloids: These are elements located along the staircase line that exhibit properties of both metals and non-metals.

  • Properties Comparison:

    • Metals:

      • State: Solids at room temperature (with the exception of Mercury, HgHg).

      • Appearance: Shiny (lustrous).

      • Conductivity: Good conductors of both heat and electricity.

      • Malleability: Malleable (can be hammered into sheets).

      • Ductility: Ductile (can be drawn into wires).

    • Non-Metals:

      • State: Can be gas, liquid, or solid at room temperature.

      • Appearance: Not very shiny (dull).

      • Conductivity: Do not conduct heat or electricity well.

      • Malleability: Brittle (tend to break or shatter when stressed).

      • Ductility: Not ductile.

Electron Patterns and Bohr Models

  • Bohr Model of e-:

    • Electrons (ee^-) orbit the nucleus in fixed energy levels.

    • The period number equals the number of energy levels in its atoms.

  • Energy Level Capacity:

    • Each energy level has a maximum capacity for electrons:

      • 1st1^{st} Energy Level: Holds up to 22 electrons.

      • 2nd2^{nd} Energy Level: Holds up to 88 electrons.

      • 3rd3^{rd} Energy Level: Holds up to 88 electrons.

    • Once an energy level is full, electrons begin filling the next available level.

  • Valence Electrons and Stability:

    • Valence electrons (ee^-) are the electrons located in the outermost shell of an atom.

    • Elements are most stable when their outer level is full.

    • This stability is the reason why atoms of different elements undergo chemical reactions to combine.

Atomic Models and Diagrams

  • Energy Level Diagrams:

    • A model representing the atom with the nucleus at the center and electrons drawn in orbits around it.

    • Elements in the same group have the same number of valence electrons.

    • Specific elements targeted for practice: HH, HeHe, LiLi, BeBe, PP, and ArAr.

  • Lewis Dot Diagrams:

    • These focus exclusively on the valence electrons.

    • The diagram consists of the element's chemical symbol surrounded by dots representing the valence electrons.

    • Example elements to draw: LiLi, BeBe, PP, ArAr, and HeHe.

Formation of Ions

  • Neutral Atoms:

    • In a neutral atom, the number of protons (p+p^+) is equal to the number of electrons (ee^-).

  • Ionization Process:

    • Elements want to lose or gain electrons in their valence shell to achieve a full shell, known as a "stable octet."

    • By reaching a full shell, they achieve an electron configuration similar to the nearest noble gas.

    • If the number of electrons does not equal the number of protons, the atom carries a charge and becomes an ION.

    • Representation: Ions are represented by the element symbol and the ion charge (e.g., Na+Na^+, N3N^{3-}, Mg2+Mg^{2+}, BrBr^-).

  • Metal Ions (Cations):

    • Metals tend to lose electrons to become positive.

    • These positive ions are called CATIONS.

    • The name of a metal ion is the same as the name of the element.

  • Non-Metal Ions (Anions):

    • Non-metals tend to gain electrons to become negative.

    • These negative ions are called ANIONS.

    • The names of non-metal ions are modified to end in the suffix "-ide" (e.g., Chlorine becomes chloride).

Ion Examples and Comparisons

  • Example C3: Magnesium Ion (Mg2+Mg^{2+}):

    • Atom vs. Ion: A neutral Magnesium atom has 1212 protons. The magnesium ion (Mg2+Mg^{2+}) loses its 22 valence electrons to achieve stability.

    • Diagram for Mg2+nuestrosMg^{2+ nuestros}:

      • Nucleus: 12p+12 p^+, 12n012 n^0.

      • Energy Levels: 2e2e^- in the first level, 8e8e^- in the second.

    • Nearest Noble Gas: The magnesium ion has the same number of electrons (1010) as Neon (NeNe).

    • Neon (NeNe) Diagram: 10p+10 p^+, 10n010 n^0; 2e2e^-, 8e8e^-.

  • Example C4: Sulfide Ion (S2S^{2-}):

    • The sulfide ion is the ionic form of Sulfur.

    • Diagram for Sulfide (S2S^{2-}):

      • Nucleus: 16p+16 p^+, 16n016 n^0.

      • Energy Levels: 2e2e^- (first level), 8e8e^- (second level), 8e8e^- (third level).

    • Nearest Noble Gas: The sulfide ion has the same number of electrons (1818) as Argon (ArAr).

    • Argon (ArAr) Diagram: 18p+18 p^+, 22n022 n^0; 2e2e^-, 8e^-$, 8e^-$$.