acids and bases
bronstead lowry acid → proton donor
bronstead lowry base → proton acceptor
lewis acid → electron acceptor
lewis base → electron donor
arrows move from lone pairs or bonds to atoms or bonds.
more dissociating = stronger acid
higher KA = stronger acid
lower pKA = stronger acid
strong acid = weak conjugate base (more stable)
equilibrium
weaker acids and bases (HIGHER PKA) are favored at equilibrium.
ATOM
when comparing atoms in the same group, the larger atom will correlate with a weaker base
when comparing atoms in the same period, the more electronegative atom will correlate with a weaker base
RESONANCE
the molecule with more resonance will be a weaker base
INDUCTION
the molecule with an inductive effect will be a weaker base.
closer to basic atom = more stable
more electronegative = more stable
more electronegative atoms = more stable
ORBITALS
SP hybridized basic atom = weaker base