EL 5
==Covalent bonding-== electrons are shared between atoms on non-metallic elements (not energetically favourable to form ions). The compound is more stable than the elements individually.
==Lone pairs-== pairs of electrons that are not involved in bonding
Calculating the lone pairs
- Work out the number of valence electrons of the element
- Work out how many of those electrons are involved in bonding to another atom
- Subtract the number of bonding electrons from the number of valence electrons
- Ass electrons for every negative charge
- Subtract electrons for every positive charge
- Divide the number by 2 to get the number of lone pairs for the element
- You have to take into account the type of bond (eg. Single, double) and the charge on the molecule.
==Dative covalent bond==- when both bonding electrons come from the same atom.
Determining shapes
In molecules, bonding pairs of electrons arrange themselves as far apart as possible.
Lone pairs have a greater repulsion than bonding pairs, therefore the presences of lone pairs can alter the shape of the molecules by pushing the bonding pairs closer together.
6 areas of electron density = octahedral molecule with a bond angle of 90 degrees
5 areas of electron density = trigonal bipyrmidal molecule with a bond angle of 120 degrees and 90 degrees
4 areas of electron density = tetrahedral molecule with a bond angle of 109.5 degrees
3 areas of electron density = trigonal planar molecule with a bond angle of 120 degrees
2 areas of electron density = linear molecules with a bond angle of 180 degrees
If one of the areas of electorn density is a lone pair it will repell the other electrons by an extra 2.5 degrees