(2) Enthalpy of a neutralization reaction (acid base reaction) with example

Steps to Complete the Acid-Base Reaction Lab

  1. Gather Materials:

    • 50 mL of 0.1 M NaOH (base)

    • 50 mL of 0.1 M HCl (acid)

    • Thermometer

    • Calorimeter (foam cup)

    • Graduated cylinder

  2. Prepare the Reactants:

    • Measure 50 mL of 0.1 M NaOH and pour it into the calorimeter.

    • Measure 50 mL of 0.1 M HCl and set it aside.

  3. Measure Initial Temperature:

    • Measure and record the initial temperature of the NaOH solution using the thermometer.

  4. Mix Reactants:

    • Quickly add the 50 mL of HCl to the NaOH in the calorimeter and mix thoroughly.

  5. Measure Final Temperature:

    • After mixing, measure and record the final temperature of the solution in the calorimeter once it stabilizes.

  6. Calculate Temperature Change (ΔT):

    • Use the formula ΔT = T_final - T_initial.

  7. Calculate Heat Absorbed by the Solution:

    • Use the formula Q_solution = mCΔT, where:

      • m = mass of the solution (100 g)

      • C = specific heat capacity of water (4.184 J/g/°C)

      • ΔT = temperature change calculated previously.

  8. Calculate Heat Absorbed by the Calorimeter:

    • Use the formula Q_calorimeter = heat capacity × ΔT, where heat capacity = 5.0 J/°C.

  9. Calculate Total Energy Change for the Reaction:

    • Calculate total heat released using Q_reaction = - (Q_solution + Q_calorimeter).

  10. Determine Moles of Limiting Reactant:


    • Calculate moles of HCl using the formula:Moles = volume (L) × concentration (moles/L).

  11. Calculate Enthalpy (ΔH):

    • Use the formula ΔH = Q_reaction / moles of limiting reactant.

  12. Record Observations:

    • Note any qualitative observations during the reaction and tabulate your results.

  13. Analyze Results:

    • Discuss the exothermic nature of the reaction and any relevant observations based on your findings.