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Atomic Bonding

Bond Energy

  • Forces Between Atoms:
      - Attractive Force (FA): Primarily electrostatic in nature as atoms approach each other.
      - Repulsive Force (FR): Arises when atoms come very close, preventing them from occupying the same space.
  • Net Force (FN): The sum of attractive and repulsive forces.
  • Equilibrium Bond Length:
      - The separation distance (r) at which the net force (FN) on the atoms is zero, indicating a stable bond.

Potential Energy of the Bond

  • Potential Energy Diagram:
      - Atoms are at the bottom of a "potential well" at equilibrium.
      - Energy Required to Break the Bond (E0): The amount of energy needed to separate the atoms, overcoming attractive forces.
      - Attractive Energy (EA): Energy due to attractive forces between two atoms.
      - Repulsive Energy (ER): Energy associated with repulsive forces as the atoms approach each other.
      - Net Energy (EN): The overall energy in the interatomic system, influenced by both attractive and repulsive energies.

Ionic Bonds

  • Formation of Ionic Bonds:
      - Occurs typically between:
        - Metallic Atom: Low electronegativity (e.g., sodium, Na).
        - Non-Metallic Element: High electronegativity (e.g., chlorine, Cl).
      - Electron Transfer:
        - An electron is transferred from Na to Cl resulting in the formation of Na+ and Cl- ions.
      - Coulombic Attraction:
        - Na+ and Cl- are strongly attracted to each other via the Coulombic force.
      - Properties of Ionic Compounds:
        - Typically very strong and stiff.
        - Hard and brittle nature.

Covalent Bonds

  • Formation of Covalent Bonds:
      - Defined as the sharing of electrons between atoms within a bond.
      - Example: Bonding between carbon atoms in diamond:
        - Each carbon atom has 4 electrons in its outer shell and bonds to 4 other carbon atoms, sharing pairs of electrons.
      - Properties of Covalent Materials:
        - Covalent bonds are strong and stiff, similar to ionic bonds in many respects.

Metallic Bonding

  • Nature of Metallic Bonds:
      - Valence Electrons:
        - Metal atoms typically possess low numbers of valence electrons (usually 1 or 2).
        - Valence electrons are not strongly attached to specific atoms and are described as being "delocalized."
      - Electron Sea Model:
        - Visual representation: An arrangement of positive ionic cores within a "sea" of delocalized electrons, allowing for conductivity and malleability.

Basic Crystallography

Lattices and Unit Cells

  • Definition of Lattice:
      - Regular pattern in which atoms are arranged.
      - To define a lattice, select one atom and identify other atoms in equivalent positions.

3D Close-Packing of Spheres

  • Hexagonal Arrangement:
      - Closest packing of identical spheres can be performed using a hexagonal arrangement analogous to snooker or pool balls.
      - Close-Packed Layer:
        - A layer of atoms in a close-packed arrangement ensures maximum density.
      - Layer Positioning:
        - The first layer of atoms can be labeled (A) and a subsequent identical layer must occupy the gaps.
        - The second layer may occupy either the B or C position, depending on the stability of the stacking scheme.
  • Hexagonal Close Packing (hcp):
      - Structure represented as ABABAB…, where layers alternate positions corresponding to A and B markings.
  • Cubic Close Packing:
      - Sequence ABCABC… is another arrangement forming a cubic structure where a third layer can occupy the C position.

3D Unit Cells

  • Representation of Structures:
      - The arrangement can be represented using unit cells:
        - Face-Centered Cubic (FCC): A unit cell structure with an atom at each corner and one at the center of each face.
        - Body-Centered Cubic (BCC): A unit cell structure with an atom at each corner and one in the center of the cube.

Interstitial Structures

  • Interstitial Spaces:
      - Gaps (interstices) in crystalline structures can accommodate smaller atoms.
      - Example: Sodium Chloride (NaCl):
        - NaCl represents a cubic-close packed arrangement of Cl- ions, where Na+ ions occupy interstitial spaces.
      - Primitive Cells:
        - A model begins with a primitive cell and a different atom in the center can represent materials such as caesium chloride.