Forces Between Atoms:
- Attractive Force (FA): Primarily electrostatic in nature as atoms approach each other.
- Repulsive Force (FR): Arises when atoms come very close, preventing them from occupying the same space.
Net Force (FN): The sum of attractive and repulsive forces.
Equilibrium Bond Length:
- The separation distance (r) at which the net force (FN) on the atoms is zero, indicating a stable bond.
Potential Energy of the Bond
Potential Energy Diagram:
- Atoms are at the bottom of a "potential well" at equilibrium.
- Energy Required to Break the Bond (E0): The amount of energy needed to separate the atoms, overcoming attractive forces.
- Attractive Energy (EA): Energy due to attractive forces between two atoms.
- Repulsive Energy (ER): Energy associated with repulsive forces as the atoms approach each other.
- Net Energy (EN): The overall energy in the interatomic system, influenced by both attractive and repulsive energies.
Ionic Bonds
Formation of Ionic Bonds:
- Occurs typically between:
- Metallic Atom: Low electronegativity (e.g., sodium, Na).
- Non-Metallic Element: High electronegativity (e.g., chlorine, Cl).
- Electron Transfer:
- An electron is transferred from Na to Cl resulting in the formation of Na+ and Cl- ions.
- Coulombic Attraction:
- Na+ and Cl- are strongly attracted to each other via the Coulombic force.
- Properties of Ionic Compounds:
- Typically very strong and stiff.
- Hard and brittle nature.
Covalent Bonds
Formation of Covalent Bonds:
- Defined as the sharing of electrons between atoms within a bond.
- Example: Bonding between carbon atoms in diamond:
- Each carbon atom has 4 electrons in its outer shell and bonds to 4 other carbon atoms, sharing pairs of electrons.
- Properties of Covalent Materials:
- Covalent bonds are strong and stiff, similar to ionic bonds in many respects.
Metallic Bonding
Nature of Metallic Bonds:
- Valence Electrons:
- Metal atoms typically possess low numbers of valence electrons (usually 1 or 2).
- Valence electrons are not strongly attached to specific atoms and are described as being "delocalized."
- Electron Sea Model:
- Visual representation: An arrangement of positive ionic cores within a "sea" of delocalized electrons, allowing for conductivity and malleability.
Basic Crystallography
Lattices and Unit Cells
Definition of Lattice:
- Regular pattern in which atoms are arranged.
- To define a lattice, select one atom and identify other atoms in equivalent positions.
3D Close-Packing of Spheres
Hexagonal Arrangement:
- Closest packing of identical spheres can be performed using a hexagonal arrangement analogous to snooker or pool balls.
- Close-Packed Layer:
- A layer of atoms in a close-packed arrangement ensures maximum density.
- Layer Positioning:
- The first layer of atoms can be labeled (A) and a subsequent identical layer must occupy the gaps.
- The second layer may occupy either the B or C position, depending on the stability of the stacking scheme.
Hexagonal Close Packing (hcp):
- Structure represented as ABABAB…, where layers alternate positions corresponding to A and B markings.
Cubic Close Packing:
- Sequence ABCABC… is another arrangement forming a cubic structure where a third layer can occupy the C position.
3D Unit Cells
Representation of Structures:
- The arrangement can be represented using unit cells:
- Face-Centered Cubic (FCC): A unit cell structure with an atom at each corner and one at the center of each face.
- Body-Centered Cubic (BCC): A unit cell structure with an atom at each corner and one in the center of the cube.
Interstitial Structures
Interstitial Spaces:
- Gaps (interstices) in crystalline structures can accommodate smaller atoms.
- Example: Sodium Chloride (NaCl):
- NaCl represents a cubic-close packed arrangement of Cl- ions, where Na+ ions occupy interstitial spaces.
- Primitive Cells:
- A model begins with a primitive cell and a different atom in the center can represent materials such as caesium chloride.