Addition polymerisation
Introduction to Addition Polymerisation
Addition polymerisation involves the transformation of monomers into long chain polymers. A polymer is made up of many repeating units of monomers, such as polyethene.
Ethanoic Acid Reactions
In the context of chemical reactions, sodium ethanoate reacts with water to yield several products. Gas A produced is hydrogen (H₂), along with alkali B, which can be either sodium hydroxide (NaOH) or sodium oxide (Na₂O). Ester C formed in the reaction is ethyl ethanoate (CH₃COOC₂H₅) with concentrated sulfuric acid (H₂SO₄) as catalyst D. Additionally, carboxylic acid salt E, also known as sodium ethanoate (CH₃COONa), is involved in the processes.
Examples of Polymers
Polymers can be found in various forms, including silk, wool, DNA, Teflon, plastics, and clothing. These materials illustrate the diversity and applicability of polymers in everyday life.
Understanding Polymers
Polymers are defined as long chain molecules created by connecting numerous smaller molecules called monomers. A useful analogy for understanding this is to think of monomers as individual paper clips, and a polymer as a chain formed by linking many paper clips together. The term "polymer" is derived from the Greek words "poly," meaning 'many,' and "mer," meaning 'unit.' These larger molecules are typically created when hundreds of monomers join together, with synthetic polymers, such as plastics, being particularly notable for their malleability under heat or pressure.
Polymer Formation
The process of polymer formation from alkenes involves hydrocarbon molecules characterized by the formula CₙH₂ₙ, which contain at least one double bond. Examples of alkenes include ethene (C₂H₄) and propene (C₃H₆). The presence of the double bond increases the reactivity of these alkenes.
Bonds in Polymers
Monomers in polymers are linked through covalent bonds, where atoms share one or more electrons, which are often illustrated as sticks in structural diagrams.
Naming Polymers
The nomenclature of polymers follows a convention where the prefix "poly" signifies 'many,' and the name in brackets corresponds to the monomer from which it is formed. For instance, the monomer ethene forms the polymer poly(ethene) or polythene, while the monomer propene leads to polypropene. Similarly, chloroethene (vinyl chloride) serves as the monomer for polyvinyl chloride.
Activities and Exercises
Educational activities can include matching various monomers to their corresponding polymers, drawing different polymer structures based on given monomers, and correcting polymer formulas. Visuals of diagrams serve as valuable tools in these exercises, further emphasizing the structures of ethene, propene, and chloroethene in their polymer forms, such as poly(ethene), poly(propene), and poly(chloroethene). Additionally, key terms related to hydrocarbons and their reactions offer further opportunities for exploration and understanding in the subject matter of addition polymerisation.