Developing a Nuclear Model of the Atom

Developing a Nuclear Model of the Atom

Section 3.1


History of Atomic Theory

  • Overview of key contributors to atomic theory:

    • Dalton (1803)

    • Thomson (1904) - positive and negative charges

    • Rutherford (1911) - nucleus

    • Bohr (1913) - energy shells

    • Schrödinger (1926) - electron cloud model


Key Models of the Atom

Electron Cloud Model

  • Darker areas indicate higher probability of finding electrons.

    • Nucleus represents the center with positive charge.

JJ Thomson's Model

  • Spherical cloud of positive charge with embedded electrons.

Rutherford's Experiment

  • Setup includes:

    • Detecting screen

    • Gold foil

    • Alpha particle emitter.


Rutherford's Model Limitations

  • Missing explanation for electron behavior and stability.


Energy Levels in Atoms

Bohr's Atomic Model

  • Electrons orbit the nucleus in fixed energy levels (n = 1, 2, 3, 4).

  • Electrons can move between levels by absorbing or releasing energy.


Spectra and Energy Levels

  • Continuous Spectrum vs. Emission Line Spectrum

  • Energy release occurs when electrons fall back to ground state.


Understanding Isotopes

Isotope Notation

  • Mass number (A) = Number of protons + Number of neutrons

  • Example: Carbon-12: 6 protons, 6 neutrons.


Average Atomic Mass Calculation

  • Calculation involves:

    • Contribution of each isotope's mass based on abundance.

  • Example for Zinc:

    • Zn-64 contributes 31.07 u

    • Zn-66 contributes 18.39 u

    • Summation of contributions for average atomic mass.


Conclusion

  • A comprehensive understanding of atomic structure includes historical models, limitations, and the role of isotopes in calculating average atomic mass.