Electron configuration

Orbitals

  • electrons are not actually particles - they can be refered to as clouds or waves of negative charge.

  • electrons occupy an areas we refer to as an orbital

  • and orbital is are volumes of space surrounding the nucleus where there is a 95% chance we can find an electron

  • for each energy level there are specific numbers of orbitals it can hold

Histroy of the orbital:

We don’t actually know exactly where the electron is ues to the uncertainty principle. BUT we can get a rough idea by calculating prbability of finding an electron around the nucleus - and use this calcualtion to find a region if space which 95% likely contains an electron.

we call this region of space and orbital


Shapes + types of orbitals:

s orbitals~

  • are spherical in shape

  • 1 orbital

  • can hold only 2 electrons

p orbitals~

  • are shaped like a dumbbell

  • 3  sublevels of orbitals

  • can hold up to 6 electrons

d orbitals~

  • various shapes

  • 5 sublevels of orbitals

  • can hold up to 10 electrons

f orbitals~

  • various shapes

  • 7 sublevels of orbitals

  • can hold up to 14 electrons

Orbital

Capacity of each orbital

Number of orbital  (Subtypes)

Total capacity

s

2

1

2×1=2

p

2

3

2×3=6

d

2

5

2×5=10

f

2

7

2×7=14

Rules

  1. Electron will occupy the orbital starting from the lowest every level if they can.

  2. Each orbital can hold up to 2 electron which will have opposite spins.

  3. Electrons are a bit repulsive so in an orbital they will each fill the subtype before pairing up.

How it works: in terms of a new way of writing electron arrangements…

Eg: write the shorthand electron configuration for Kr (Krypton)

2.8.8.8.8.2 → however this means that it is in Group 2, Period 6… which a completely different element.

sooooo instead we do this:

1s2 2s2 2p6 3s2 3p6 4s2 3d104p6

here are some other examples..

Old way :(

New way :)

Lithium(3)

2.1

1s2 2s1

Carbon(6)

2.4

1s2 2s2 2p2

Flourine (9)

2.7

1s2 2s2 2p5

Magnesium (12)

2.8.2

1s2 2s2 2p6 3s2

Chlorine (17)

2.8.7

1s2 2s2 2p6 3s2 3p5

Titanium (22)

1s2 2s2 2p6 3s2 3p6 4s2 3d2

Nickel (28)

1s2 2s2 2p6 3s2 3p6 4s2 3d8

Bromine (35)

1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p5

Strontium (38)

1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 4d2

Rhodium(45)

1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 4d9