Electron configuration

Orbitals

  • electrons are not actually particles - they can be refered to as clouds or waves of negative charge.

  • electrons occupy an areas we refer to as an orbital

  • and orbital is are volumes of space surrounding the nucleus where there is a 95% chance we can find an electron

  • for each energy level there are specific numbers of orbitals it can hold


Histroy of the orbital:

We don’t actually know exactly where the electron is ues to the uncertainty principle. BUT we can get a rough idea by calculating prbability of finding an electron around the nucleus - and use this calcualtion to find a region if space which 95% likely contains an electron.

we call this region of space and orbital


Shapes + types of orbitals:

s orbitals~

  • are spherical in shape

  • 1 orbital

  • can hold only 2 electrons


p orbitals~

  • are shaped like a dumbbell

  • 3  sublevels of orbitals

  • can hold up to 6 electrons


d orbitals~

  • various shapes

  • 5 sublevels of orbitals

  • can hold up to 10 electrons


f orbitals~

  • various shapes

  • 7 sublevels of orbitals

  • can hold up to 14 electrons


Orbital

Capacity of each orbital

Number of orbital  (Subtypes)

Total capacity

s

2

1

2×1=2

p

2

3

2×3=6

d

2

5

2×5=10

f

2

7

2×7=14


Rules

  1. Electron will occupy the orbital starting from the lowest every level if they can.

  2. Each orbital can hold up to 2 electron which will have opposite spins.

  3. Electrons are a bit repulsive so in an orbital they will each fill the subtype before pairing up.



How it works: in terms of a new way of writing electron arrangements…


Eg: write the shorthand electron configuration for Kr (Krypton)

2.8.8.8.8.2 → however this means that it is in Group 2, Period 6… which a completely different element.


sooooo instead we do this:

1s2 2s2 2p6 3s2 3p6 4s2 3d104p6


here are some other examples..


Old way :(

New way :)

Lithium(3)

2.1

1s2 2s1

Carbon(6)

2.4

1s2 2s2 2p2

Flourine (9)

2.7

1s2 2s2 2p5

Magnesium (12)

2.8.2

1s2 2s2 2p6 3s2

Chlorine (17)

2.8.7

1s2 2s2 2p6 3s2 3p5

Titanium (22)

…

1s2 2s2 2p6 3s2 3p6 4s2 3d2

Nickel (28)

…

1s2 2s2 2p6 3s2 3p6 4s2 3d8

Bromine (35)

…

1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p5

Strontium (38)

…

1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 4d2

Rhodium(45)

…

1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 4d9