Chemistry

Theme: Carbon and Its Compounds

Introduction to Carbon

  • Importance of Carbon: Carbon is a vital non-metallic element in Earth's crust.

    • Symbol: C

    • Atomic Number: 6

    • Mass Number: 12

  • Presence of Carbon: Found in daily items such as food, clothing, and pencil lead.

Carbon Compounds and Organic Chemistry

  • Approximately 85% of all known compounds contain carbon; Organic Chemistry focuses on carbon compounds.

    • Examples: vinegar, wool, starch, etc.

  • Hydrocarbons: Compounds consisting only of carbon and hydrogen, crucial for fuels and energy.

  • Carbon is essential for life, present in both free (diamond, graphite) and combined states (coal, petroleum).

  • The word carbon is derived from the Latin word" carbo," meaning charcoal, which reflects its historical association with burning organic materials.

Allotropy and Allotropes of Carbon

  • Allotropy: The property of an element to exist in multiple forms with identical chemical properties but different physical properties.

    • Examples: Diamond and graphite

  • allotropes: different physical forms of an element. they have different physical forms but the same chemical properties.

  • Reasons for Allotropy:

    • Different preparation methods

    • Energy variations involved

    • Diverse atomic arrangement

Types of Coal

  1. Peat

    • Youngest form; 50-60% carbon; partially decayed plant matter.

    • Burns slowly, leaving ash.

  2. Lignite

    • Soft, brown coal with 60-70% carbon.

    • Harder than peat, burns with lesser soot.

  3. Bituminous

    • Most abundant type; 75-80% carbon. Used for heating.

  4. Anthracite

    • Hardest coal with 90-95% carbon, high heat generation, burns slowly with minimal smoke.

  • Uses of Coal:

    • Fuel for electricity and cooking, reducing agent in metal extraction, organic compound source.

Coke

  • The black porous solid residue left after the destructive distillation of coal. Contains 95 to 98% of free carbon and is free from volatile impurities. Bad conductor of heat and electricity.

  • Destructive distillation: coal is heated in the absence of air. It results in the formation of coke, coal gas, etc.

Kajal Preparation Activity

  • Aim: To make kajal

  • Materials: Mustard oil, lamp, cotton wick, metal plate

  • Observation: Lampblack deposited on the plate from the flame.

Carbon and Its Occurrence

  • Coal: Natural form of amorphous carbon found deep within the Earth.

    • Formation: From decomposed plants over millions of years under pressure.

  • Carbonisation: Process converting organic matter into coal under heat and pressure.

Types of Charcoal

  1. Wood Charcoal: Produced via wood distillation; black, porous.

  2. Sugar Charcoal: Formed from sugar using acid.

  3. Animal Charcoal: Derived from bones, used for purification.

  4. Lampblack: Byproduct of burning hydrocarbons, used in various applications. Contains 98 to 99% of carbon

Fullerene

  • A crystalline form with 20-900 carbon atoms; the common type known as C60 resembles a soccer ball.

  • Preparation: From vaporised graphite in helium.

  • Properties: Soluble in many solvents, stable, can become superconductive in some instances.

Graphite

  • Conductivity: Good conductor of electricity due to free valence electrons.

  • Structure: Hexagonal layers; soft and slippery due to weak interlayer binding.

  • Uses: In pencils, lubricants, batteries, and nuclear reactors.

Diamond

  • Properties: Transparent and colorless, hardest natural substance (3.5 g/cm³), good light refractor (high refractive index).

  • Formed under extreme conditions; both natural and synthetic diamonds exist.

  • Uses: In cutting tools, jewelry, and specific scientific applications.

Differences between Graphite and Diamond

Property

Graphite

Diamond

Color

Greyish-black, opaque

Colorless, transparent

Structure

Hexagonal

Tetrahedral

Hardness

Soft and slippery

Hardest substance

Conductivity

Good conductor

Poor conductor

Density

2.3 g/cm³

3.5 g/cm³

Conclusion

  • Carbon: Vital element with diverse allotropes and numerous applications in daily life and industry.

  • Understanding its properties and behavior is crucial for chemistry and various fields of study.

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