Ceramics: Clay

Introduction

  • Clay: a type of fine-grained natural soil material that contains hydrous aluminium phyllosilicates (clay minerals) that develops plasticity when wet.
  • Silicate: any member of a family of anions consisting of silicon and oxygen
      * The family includes orthosilicate, metasilicate and pyrosilicate.
  • Phyllosilicates: sheet silicate minerals, formed by parallel sheets of silicate tetrahedra with Si2O5 or a 2:5 ratio.

Firing of Clay

  • 100C-125C: Residual (unbound) water; kaolin is transformed into metakaolin
  • 200C-1000C: Organic material burns off
  • 350C-525C: Lattice water (water a part of the crystalline structure) is removed; no shrinkage occurs
  • 573C: Low quartz is transformed into high quartz
  • 790C: Magnesium carbonate decomposes to magnesium oxide and carbon dioxide
  • 870C: Quartz is transformed into tridymite
  • 880C: Calcium carbonate decomposes to calcium oxide and carbon dioxide
  • 950C: Metakaolin is transformed into a defect, spinel-type structure
  • 1000C-1250C: Mullite is formed from the feldspar present
  • 1100C-1300C: Calcium sulfate and magnesium sulfate decompose
  • 1470C: Tridymite is transformed into cristobalite
  • All these transitions are very slow processes
  • The volume change (shrinkage):  10 – 15 %
  • Ceramic: combination of one or more metals or semimetals (silicon) with oxygen, linked by ionic and covalent bonds into a polymeric matrix.
  • Types of ceramic pottery: earthenware, stoneware, bone china, porcelain and vitrified pottery.
  • Fired ceramic objects are porous; this is why they are coated with a glaze (properties identical to glasses).  It make pottery non-porous and watertight, it improves the strength of the object and it adds additional visual effect.

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