Ceramics: Clay
Introduction
- Clay: a type of fine-grained natural soil material that contains hydrous aluminium phyllosilicates (clay minerals) that develops plasticity when wet.
- Silicate: any member of a family of anions consisting of silicon and oxygen
* The family includes orthosilicate, metasilicate and pyrosilicate. - Phyllosilicates: sheet silicate minerals, formed by parallel sheets of silicate tetrahedra with Si2O5 or a 2:5 ratio.
Firing of Clay
- 100C-125C: Residual (unbound) water; kaolin is transformed into metakaolin
- 200C-1000C: Organic material burns off
- 350C-525C: Lattice water (water a part of the crystalline structure) is removed; no shrinkage occurs
- 573C: Low quartz is transformed into high quartz
- 790C: Magnesium carbonate decomposes to magnesium oxide and carbon dioxide
- 870C: Quartz is transformed into tridymite
- 880C: Calcium carbonate decomposes to calcium oxide and carbon dioxide
- 950C: Metakaolin is transformed into a defect, spinel-type structure
- 1000C-1250C: Mullite is formed from the feldspar present
- 1100C-1300C: Calcium sulfate and magnesium sulfate decompose
- 1470C: Tridymite is transformed into cristobalite
- All these transitions are very slow processes
- The volume change (shrinkage): 10 – 15 %
- Ceramic: combination of one or more metals or semimetals (silicon) with oxygen, linked by ionic and covalent bonds into a polymeric matrix.
- Types of ceramic pottery: earthenware, stoneware, bone china, porcelain and vitrified pottery.
- Fired ceramic objects are porous; this is why they are coated with a glaze (properties identical to glasses). It make pottery non-porous and watertight, it improves the strength of the object and it adds additional visual effect.
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