hydrates

Covalent Network Solids

  • Formed from elements in the Carbon group due to their ability to make 4 covalent bonds.

  • Examples:

    • Silicon: Semiconductor, forms 3-D networks similar to carbon.

    • SiO2 (Quartz).

Hydrates: Guided Notes

  • Solid crystals containing water.

Vocabulary

  • Hydrated: Contains water in its structure.

  • Anhydrous: Salt compound of a hydrate without water attached.

  • Hydrophilic: Water-loving; can mix and interact with water.

  • Hydrophobic: Molecules that do not mix with water.

  • Desiccant: A substance that absorbs water controlling moisture.

Introduction to Hydrates

  • Chemical compounds that contain water in their crystal structure, essential for the chemical formula.

  • Specific number of water molecules associated with each formula unit.

Naming Practice

  • Examples of Compounds:

    • Lithium chloride tetrahydrate: LiCl·4H₂O

    • Magnesium sulfate heptahydrate: MgSO4·7H₂O

    • Barium hydroxide octahydrate: Ba(OH)₂·8H₂O

    • Sodium carbonate decahydrate: Na₂CO₃·10H₂O

  • Anhydride/Anhydrous:

    • (Noun) The light blue powder is the anhydride.

    • (Adjective) Anhydrous copper (II) sulfate left after heating.

Types of Hydrates

  1. Efflorescent Hydrates:

    • Weakly bonded water, easily lost, high vapor pressure, can become anhydrous in low ambient air pressure.

  2. Hygroscopic Hydrates:

    • Strongly bonded water, easily gains moisture, low vapor pressure, often used as desiccants.

  3. Deliquescent Hydrates:

    • Hygroscopic substances that absorb enough moisture to dissolve and form a liquid solution.


% \text{ water} = \frac{(18.029)(3)}{136.1099} \times 100 = 39.72 \%