11TH GRADE AP BIOLOGY - Unit 1 ___ Notes
Lesson 1: Structure of Water and Hydrogen Bonding
All life needs water to survive and is made up of water
H2O has 2 lone electron pairs on the oxygen
O is electronegative - hogs electrons
Electrons are always moving so there is no definite structure
Connections of H2O’s to other H2O’s is called a hydrogen bond
Water Properties: water’s ability to take in heat, water’s ability to regulate temperature (specific heat), why lakes don’t freeze over, properties of evaporative cooling, surface tension, adhesion, and cohesion, and its ability to be a solvent
Water is polar
Hydrophilic - anything that interacts with water and is dissolved by it
Hydrophobic - things that don’t interact and aren’t dissolved by water
In a container, water forms a meniscus
Concave - fluid is more attracted to the container
Molecules in glass are polar → water has kinetic nrg → stick/adhesion
Cohesion - something sticking to itself – H2O
Capillary action - the movement of water within the spaces of a porous material due to the forces of adhesion, cohesion, and surface tension
Hydrogen bonds keep water at a standard temp and pressure
Water molecules are cohesive - attracted
Surface tension - surface water can become denser and have a stronger IMF than the body and is less attracted to the surrounding air
Helps resist rupture when water is under stress or pressure
Adhesion - attraction of molecules of one kind for molecules of a different kind
Allows water to climb upward through a glass (capillary action)
Water is a solvent; easy for things to be dissolved in water
Its polarity makes it able to dissolve lots of molecules (ex. NaCl with H2O)
Opposites attract
If something is an ion or has polarity it will be easy to dissolve in water
Molecules that don’t have charge or aren’t polar will not dissolve in water (ex. hexane)
Solute - something that can dissolve
Hydrophilic - water-loving
Hydrophobic - water-fearing
Liquid water ~ hydrogen bonds are constantly breaking and forming
Heat of kinetic nrg breaks these bonds
Water vapor ~ when heat is raised the kinetic nrg breaks the bonds completely and the gas flows to the atmosphere
When temperatures drop or freeze water molecules form a crystal structure - ice; which is less dense than liquid water → water expands
Solidification - allows molecules to pack more tightly than in liquid form, giving the solid a greater density than the liquid
Occurs when there are drops in temp and kinetic nrg
Specific heat capacity - amount of heat needed to raise the temperature of one gram of a substance by one degree Celsius → water needs a lot of heat
calorie
Can minimize changes in temp
Heat of vaporization - amount of energy needed to change one gram of a liquid substance to a gas at constant temperature → water needs a lot of heat → 100 C
Evaporative cooling - as water molecules evaporate, the surface they evaporate from gets cooler
Lesson 2: Elements of Life
Different substances have different properties (reflection, certain color, certain temps = certain states, react with each other, etc.)
If you break down carbon to its simplest form, what is it? = atom
Pure substances - elements (lead, carbon, gold, etc.)
atom - most basic unit of elements
All atoms are made up of more particles that if changed, change the whole element
have specific chemical and physical properties and cannot be broken down into other substances through ordinary chemical reactions
In hair, the width of carbon atoms is approximately 1 million
Protons and neutrons are the nucleus of an atom
Proton - defines an element = atomic number
Positive charfe
Electron - negative charge
Can change
Buzz around nucleus
Neturton - neutral
Can change
Protons and electrons attract
If lose an electron in atom then the atom will have a positive next charge
Humans could be referenced as the byproduct of chemical and electrical interactions between a very, very large number of nonliving atoms
Matter - anything that occupies space or mass
Carbon is essential for life – carbon-based life
Backbone of imp mlc such as proteins, DNA, RNA, sugars, and fats
Valence electrons do the reaction and fulfill the octet rule
Methane is an organic molecule (macromolecules - contain carbon atoms) or hydrocarbon - og mlc consisting of carbon and hydrogen → covalent bonding
Forms a tetrahedral shape
Octane - msr of a fuel's ability to resist combustion
Carbon can create lattice structures
Functional groups - chemical motifs, or patterns of atoms, that display consistent “function” (properties and reactivity) regardless of the exact molecule they are found in
Hydroxyl (polar) group combined with carboxyl group = alcohol
Hydroxyl can be dissolved into water through H-bonding
Sulfydral group - still polar but not as polar
R is abbreviation for “rest of molecule” - mainly carbon backbone
Carbonyl group is also polar
Carboxyl groups donate hydrogens so are viewed as acidic
Elements building blocks
Amino acids - building blocks of proteins
Made of C, H, O, N, sometimes P
ATP - a molecule that stores and releases energy in cells, making it essential for life
Triglyceride - fat molecule used for nrg storage
Backbone of DNA → 5-C sugars and phosphate groups
Lesson 3: Introduction to biological macromolecules
Bonding of atoms
Bonding is important as atoms want to become stable to support life
Ionic bonding - attraction of 2 oppositely charged ions
Cations - positbley charged elctrons after losing an electron
Anions - negatively charged electrons after gaining an electron
Electron transfer - one atoms loses and electron and one atoms gains one
Covalent bonding - sharing of electrons between 2 atoms
In the case of water – oxygen is more electrongetive which causes electrons to want to be with oxygen
Polar covalent bond - atoms with different electrongeatives share electrons
Nonpolar covalent bond - 2 atoms of the same of different element that share electrons almost equally
Key to the carbon-based molecules such as DNA and proteins
Hydrogen bonds - a weak bond between 2 molecules resulting from an electrostatic attraction between a proton in 1 molecule and an electronegative atom in the other
Lond Dispersion Force - weak attraction between mlc and atoms that depend on temporary imbalances in electron distribution
Van der Waals force - intermolecular interactions that do not involve covalent bonds or ions
LDF and H-bonds follow this
Strong covalent bonds hold chemical building blocks to make strand of DNA
Weak covalent bonds hold together the 2 strands of DNA → keep stable
Macromolecules – 4 groups
Carbohydrates (sugars), lipids (fats), proteins, and nucleic acid (DNA and RNA)
Carbohydrates - large nrg storage
Lipids - some key structural components of cell membrane
Proteins - structural support and catalyzing metabolic reactions or receiving and transmitting signals
Nuclec acid - store and transfer genetic info
Polymer - long chain of monomers (subunit of polymers)
Dehydration synthesis - 2 monomers form a covalent bond realsing a water mlc in the process
All macromolecules can contain multiple different monomers that create a specific sequence
Hydrolisis rxn - bond is broken with the addition of a water molecule
Enzyme catalyze speed up dehydration synthesis and hydrolysis rxn