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Dalton's Atomic Theory
1) elements are composed of atoms. 2) atoms of same element are identical, but differ from other elements. 3) elements can mix together in integer or simple fraction ratios 4) a chemical reaction involves only the separation, combination, or rearrangement of atoms, not their creation or destruction
uncuttable or indivisible
atomos
law of definite proportions
different samples of the same compound always contain its constituent elements in the same proportion by mass
Law of Multiple Proportions
If two elements combine to form different compounds, the masses of one element that combine with a fixed mass of the other element are in ratios of small whole numbers
Law of Conservation of Mass
Matter is not created nor destroyed in any chemical or physical change
atom
the basic unit of an element that can enter into chemical combination
subatonic particles
protons, neutrons, electrons
Radiation
the emission and transmission of energy through space in the form of waves
JJ Thomson
used the cathode ray tube to discover electrons
coulumb
SI unit of electric charge
Robert Millikan
1909 oil drop experiment, calculated the charge and mass of electrons
William Roentgen
discovered x-rays in 1895
Radioactivity
The spontaneous emission of radiation by an unstable atomic nucleus
alpha, beta, gamma
3 types of radiation
alpha rays
consist of positively charged particles and are deflected by a positively charged plate
beta rays
consist of negatively charged particles and are deflected by a negatively charged plate
gamma rays
have no charge and are unaffected by external electric or magnetic fields
Plum Pudding Model
J.J Thomsons model of an atom, in which he thought electrons were randomly distributed within a positively charged cloud
James Chadwick
Discovered the neutron
neutron
the particles of the nucleus that have no charge, and a mass slightly larger than that of a proton
mass number
the sum of the number of neutrons and protons in an atomic nucleus
isotope
Atoms of the same element that have different numbers of neutrons
protons and electrons
chemical properties are determined primarily by these two subatomic particles
physical and chemical properties
elements in the periodic table are grouped by their similar...
periods
Horizontal rows on the periodic table
groups or families
Vertical columns on the periodic table
metals, nonmetals, metalloids
three classes of elements
metal
good conductor of heat and electricity
Nonmetal
an element that is a poor conductor of heat and electricity
Metalloid
An element that has some characteristics of both metals and nonmetals
alkali metals
Group 1
alkaline earth metals
Group 2
Halogens
Group 7A
noble gases
Group 8A
Molecule
aggregate of at least two atoms in a definite arrangement held together by chemical forces
diatomic molecule
A molecule consisting of only two atoms
polyatomic molecule
a molecule that consists of more than two atoms
ion
An atom or group of atoms that has a positive or negative charge.
Cation
A positively charged ion
Anion
A negatively charged ion
ionic compound
A compound that consists of positive and negative ions
monatomic ion
an ion formed from only one atom
polyatomic ion
an ion made of two or more atoms
molecular formula
shows the exact number of atoms of each element in the smallest unit of a substance
Allotrope
one of two or more distinct forms of an element
structural formula
shows how atoms are bonded to one another in a molecule
empirical formula
tells us which elements are present and the simplest whole-number ratio of their atoms
organic compounds
Compounds that contain carbon, usually in combination with elements such as hydrogen, oxygen, nitrogen, and sulfur
binary compound
a compound composed of two elements
ternary compound
a compound composed of three elements
transition metals
groups 1B, 3B-8B
acid
A substance that increases the hydrogen ion concentration of a solution.
Oxoacids
acids that contain hydrogen, oxygen, and another element
Base
A substance that decreases the hydrogen ion concentration in a solution.
hydrate
A compound that has a specific number of water molecules bound to its atoms
ionic compounds, molecular compounds, acids and bases, and hydrates
What are the four major categories of inorganic compounds?
oxoanion
an anion derived from an oxoacid
bromic acid, hypobromous acid
HBrO3 -> HBrO (name before and after)
nitric acid, nitrous acid
HNO3-> HNO2 (name before and after)
chloric acid, perchloric acid
HClO3-> HClO4 (name before and after)
Stock system
A method for naming ions of elements that can form more than one possible positive charge by using a Roman numeral after the ion name to denote the ion's charge.
C=(F-32)x5/9
Celsius to Fahrenheit conversion
carbonic acid, carbonate
H2CO3-> CO3- (name before and after)
chlorous acid, chlorite
HClO2-> ClO2-
"per-ic" acid
addition of one O atom to the "-ic" acid changes the acid's name to
"-ous" acid
Removal of one O atom from the "-ic" acid changes the acid's name to
"hypo...-ous" acid
Removal of two O atoms from the "-ic" acid changes the acid's name to
"-ate"
When all the H ions are removed from the "-ic" acid, the anion's name ends with
"-ite"
When all the H ions are removed from the "-ous" acid, the anion's name ends with
atomic mass
The average mass of all the isotopes of an element
atomic mass unit
a mass exactly equal to one twelfth the mass of a carbon-12 atom
mole
the amount of a substance that contains as many elementary entities (atoms, molecules, or other particles) as there are atoms in exactly 12 g of carbon-12 isotope
molar mass
the mass in grams of one mole of a substance
molecular mass
the sum of the atomic masses in the molecule
percent composition by mass
the percent by mass of each element in a compound
chemical reaction
the process by which one or more substances change to produce one or more different substances
Stoichiometry
the quantitative study of reactants and products in a chemical reaction
mole method
the stoichiometric coefficients in a chemical equation can be interpreted as the number of moles of each substance
stoichiometric amounts
in the proportions indicated by the balanced equation
limiting reagent
the reactant that will be exhausted first in a chemical reaction
excess reagent
a reagent present in a quantity that is more than sufficient to react with a limiting reagent; any reactant that remains after the limiting reagent is used up in a chemical reaction
theoretical yield
the amount of product that would result if all the limiting reagent reacted
actual yield
the amount of product actually obtained from a reaction
percent yield
the proportion of the actual yield to the theoretical yield
6.022*10^23
Avogadro's number
6.022*10^23amu
One gram is equal to how many amu?
1.661*10^-24g
how many grams are in one amu
Avogadro's number
number of representative particles in a mole, 6.02 X 10^23
Solute
the substance present in a smaller amount
Solution
A homogeneous mixture of two or more substances
Solvent
the substance present in the larger amount
Electrolyte
a substance that, when dissolved in water, results in a solution that can conduct electricity
nonelectrolyte
does not conduct electricity when dissolved in water
Hydration
the process in which an ion is surrounded by water molecules arranged in a specific manner
reversible reaction
a reaction that can occur in both directions
precipitation reaction
a reaction which results in the formation of an insoluble product or precipitate
precipitate
an insoluble solid that separates from the solution
metathesis reaction
a reaction that involves the exchange of parts between two compounds
Solubility
the maximum amount of solute that can dissolve in a given amount of solvent at a given temperature
molecular equation
the formulas of the compounds are written as though all species existed as molecules or whole units