Knowt 6 - Electric Structure & Periodic Properties

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50 Terms

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Amplitude

Extent of displacement caused by a wave

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Electromagnetic radiation

Energy transmitted by waves with electric and magnetic components

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Electromagnetic spectrum

Range of energies from radio to gamma rays

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Frequency (ν)

Number of wave cycles per unit time

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Hertz (Hz)

Unit of frequency as cycles per second

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Intensity

Wave energy property related to amplitude, like brightness or loudness

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Interference pattern

Alternating bright and dark fringes from wave interference

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Line spectrum

Discrete wavelengths emitted by excited atoms

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Photon

Smallest packet of electromagnetic radiation, a light particle

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Wave

Oscillation transporting energy over time or space

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Wavelength (λ)

Distance between consecutive wave peaks or troughs

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Excited state

Energy level higher than the ground state

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Ground state

Lowest possible energy state for electrons

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Atomic orbital

Mathematical function describing electron behavior in an atom

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Electron density

Probability of finding an electron in a region, squared wavefunction value

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Heisenberg uncertainty principle

Impossible to know both position and momentum exactly

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Node

Point of zero amplitude in a standing wave

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Orbital diagram

Box representation of electron configuration

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Quantization

Restriction of properties to discrete values

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Quantum mechanics

Study of matter using quantization, wave-particle duality, and uncertainty

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Quantum number

Specific value characterizing electron arrangement

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Standing wave

Localized wave with discrete wavelengths from boundary conditions

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Wave-particle duality

Particles exhibit both wave and particle properties

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Aufbau principle

Electron configuration built by adding electrons to subshells in atomic number order

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Core electron

Electron in inner shells

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Degenerate orbitals

Orbitals with the same energy

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Electron configuration

Listing of electron occupancy in shells and subshells

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s orbital

Spherical region for l=0 orbitals

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p orbital

Dumbbell-shaped region for l=1 orbitals

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d orbital

Four-lobed or dumbbell-torus region for l=2 orbitals

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f orbital

Multilobed region for l=3 orbitals

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Hund’s rule

Single electrons occupy subshell orbitals before pairing, with same spin

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Principal quantum number (n)

Number specifying electron shell

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Secondary (angular momentum) quantum number (l)

mber distinguishing orbital shapes

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Magnetic quantum number (ml)

Number indicating orbital orientation

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Spin quantum number (ms)

Number for electron spin direction (+1/2 or -1/2)

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Pauli exclusion principle

No two electrons share all four quantum numbers

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Shell

Orbitals with the same principal quantum number

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Subshell

Orbitals with same n and l values

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Valence electrons

Electrons in outer shells

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Valence shell

High-energy outer shells

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Covalent radius

Half the distance between nuclei of bonded identical atoms

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Electron affinity

Energy change from adding an electron to a gaseous atom or ion

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Ionization energy

Energy to remove an electron from a gaseous atom or ion

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Isoelectronic

Atoms or ions with identical electron configurations

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Speed of Light Constant

c = 2.998 × 108 m/s

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Planck’s Constant

h = 6.626 × 10-34 J∙s

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Speed of Light Equation

c = λν

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Planck’s Energy Equation

E = hν

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Heisenberg’s Uncertainty Principle Equation

∆x ∙ ∆px ≥ h/4π

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