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Amplitude
Extent of displacement caused by a wave
Electromagnetic radiation
Energy transmitted by waves with electric and magnetic components
Electromagnetic spectrum
Range of energies from radio to gamma rays
Frequency (ν)
Number of wave cycles per unit time
Hertz (Hz)
Unit of frequency as cycles per second
Intensity
Wave energy property related to amplitude, like brightness or loudness
Interference pattern
Alternating bright and dark fringes from wave interference
Line spectrum
Discrete wavelengths emitted by excited atoms
Photon
Smallest packet of electromagnetic radiation, a light particle
Wave
Oscillation transporting energy over time or space
Wavelength (λ)
Distance between consecutive wave peaks or troughs
Excited state
Energy level higher than the ground state
Ground state
Lowest possible energy state for electrons
Atomic orbital
Mathematical function describing electron behavior in an atom
Electron density
Probability of finding an electron in a region, squared wavefunction value
Heisenberg uncertainty principle
Impossible to know both position and momentum exactly
Node
Point of zero amplitude in a standing wave
Orbital diagram
Box representation of electron configuration
Quantization
Restriction of properties to discrete values
Quantum mechanics
Study of matter using quantization, wave-particle duality, and uncertainty
Quantum number
Specific value characterizing electron arrangement
Standing wave
Localized wave with discrete wavelengths from boundary conditions
Wave-particle duality
Particles exhibit both wave and particle properties
Aufbau principle
Electron configuration built by adding electrons to subshells in atomic number order
Core electron
Electron in inner shells
Degenerate orbitals
Orbitals with the same energy
Electron configuration
Listing of electron occupancy in shells and subshells
s orbital
Spherical region for l=0 orbitals
p orbital
Dumbbell-shaped region for l=1 orbitals
d orbital
Four-lobed or dumbbell-torus region for l=2 orbitals
f orbital
Multilobed region for l=3 orbitals
Hund’s rule
Single electrons occupy subshell orbitals before pairing, with same spin
Principal quantum number (n)
Number specifying electron shell
Secondary (angular momentum) quantum number (l)
mber distinguishing orbital shapes
Magnetic quantum number (ml)
Number indicating orbital orientation
Spin quantum number (ms)
Number for electron spin direction (+1/2 or -1/2)
Pauli exclusion principle
No two electrons share all four quantum numbers
Shell
Orbitals with the same principal quantum number
Subshell
Orbitals with same n and l values
Valence electrons
Electrons in outer shells
Valence shell
High-energy outer shells
Covalent radius
Half the distance between nuclei of bonded identical atoms
Electron affinity
Energy change from adding an electron to a gaseous atom or ion
Ionization energy
Energy to remove an electron from a gaseous atom or ion
Isoelectronic
Atoms or ions with identical electron configurations
Speed of Light Constant
c = 2.998 × 108 m/s
Planck’s Constant
h = 6.626 × 10-34 J∙s
Speed of Light Equation
c = λν
Planck’s Energy Equation
E = hν
Heisenberg’s Uncertainty Principle Equation
∆x ∙ ∆px ≥ h/4π