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chem 2023
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Aufbau Principle
Electrons occupy lowest energy levels first
Pauli Exclusion Principle
No two electrons can have the same set of quantum numbers, must have opposite spins, and only two per orbital
Hund’s Rule
Every orbital in a sublevel should be occupied with a single electron before orbitals are doubled up
Bohr Model
Proposed the electron is only found in specific circular paths around the nucleus (fixed energy)
Energy levels are not equally spaced (higher energy: closer together)
Model is based on the movement of 1 electron
Drawing a Bohr Model
2 - 8 - 8 -18
Period represents the # of energy levels
The Nature of Light
High energy → Short Wavelength (violet)
Low energy → Long Wavelength (red)
Frequency
The number of wave cycles to pass through a given point in a certain amount of time
Wavelength
Distance between crests
Speed of Light
3.00 × 108 m/s
Calculate wavelength/frequency
3.00 × 108 m/s = Wavelength x Frequency
Planck’s Constant
6.626×10-34
Calculate Energy
energy = planck’s constant x frequency
Photon
Particle of light with a certain amount of energy
Photoelectric Effect
Electrons gain energy and are ejected from metals when light is shined on them
Heisenberg Uncertainty Principle
It is impossible to simultaneously determine the position AND velocity of an electron
Photons of light can randomly known an electron off course (measure, position, velocity changes)
Double Slit Experiment
Demonstrates the wave-particle duality of light and matter.
It involves shining a beam of particles or light through two closely spaced slits onto a screen. The resulting pattern on the screen shows an interference pattern, indicating that the particles or light waves behave as both particles and waves.
De Broglie’s Contributions
Introduced the idea that particles, such as electrons, could be described not only as particles but also as waves
Quantum Mechanical Model
Based on math
Energy is still quantized
BUT no specific path for the electrons
Schrodinger
Treated electrons as diffuse waves
Based completely on probability
Principal Quantum Number (n)
Number that specifies the properties and locations of electrons in orbital
As n increases, the AVERAGE distance from the nucleus increases (and so does the energy)
Each can hold a different number of electrons
Atomic Orbital
Represent probability of electron location
Threshold Frequency
refers to the minimum frequency of light required to initiate the photoelectric effect
The frequency at which electrons in a material start to be emitted when exposed to light