arenes physical properies and reactivity + electrophilic substitution

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12 Terms

1
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why do arenes have high melting points

benzene has a flat hexagonal molecules that pack closely together making it harder to seperate

2
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what do arenes mix with

other hydrocarbons and non polar solvents

3
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two factors that are important in reactivity of aromatic compounds

  • ring of high electron density, that has delocalised bonding and can be attacked by electrophiles

  • aromatic ring is very stable, delocalisation energy is needed to break ring

4
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what feature does an aromatic compound produce

smoky flame

5
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show electrophilic substitution

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6
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Nitration equation

H2SO4 + HNO3 → NO2+ + HSO4- + H2O

7
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show nitration of benzene + name of product formed

nitrobenzene

<p>nitrobenzene</p>
8
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why is sulphuric acid a catalyst

HSO4- reacts with H+ to regenerate H2SO4

9
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importance of nitrated arenes

explosives + industrial dyes

10
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What catalyst does the Friedel-Craft acylation reaction use

aluminium chloride cataylst

11
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Show equation for friedel-craft acylation reaction

AlCl3 + RCOCl → RCO+ + AlCl4-

12
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show friedel crafts reaction mechanism + name of product formed

phenylethanone

<p>phenylethanone</p>