SBI4U --U2 - BIO CHEMISTRY

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ionic bonds

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ionic bonds

transferring one/more electrons from one atom to another

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Covalent bonds

sharing electrons between atoms

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cation

losing an electrons becoming a positive charge

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anion

gaining one/ more electron becoming a negative charge

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double covalent bond

sharing two pairs of shared valence electrons

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covalent bond shared equally

non-polar covalent

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example of non-polar covlaent

chlorine molecules

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electrons shared unequally; electronegativity difference that does not equal zero

polar covalent

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is water a polar molecule

True

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hydrogen bonding

the attraction between water molecules

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hydrophilic

compounds that interact with water by dissolving in it

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hydrophobic

compounds not interacting withing water

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what compounds are hydrophobic and what bonds can they not form

non-polar; hydrogen bonds

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Ex. why does NaCl dissolve in water?

It because chloride ions and sodium ions attract water molecules

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isomers

several organic compounds that can have the same molecular formula but w/ different structures

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example of isomers

glucose, fructose, galactose

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2 types of isomers

structual & stereoisomers

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structural isomer

two or more compounds w/ same atoms bonded differently

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Stereoisomer

two or more compounds w/ their atoms bonded in the same wya, but w/ atoms arranged differently in space

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stereoisomers can be..

geometric or optical

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Geometric isomer definition and example

can have very different physical properties but have the same chemical properties. ex glucose and galactose

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Optical isomer def and example

non-superimposable mirror images of each other, have similar chemical and physical properties but enzymes/proteins on the cell membrane can distinguish between them

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functional groups

many complex molecules containing groups of atoms with characteristic chemical properties

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types of functional groups

hydroxyl, carbonyl, carboxyl, amino, sulfhydryl, phosphate

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chemical formula for carbohydrates

(CH2O)n ; n= # of carbon atoms in the carbohydrate

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carbs can be simple

monomer glucose

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If # of carbon atoms in carbs are low (3-7) then its a...

monosaccharide

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five carbon sugar

pentose

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glucose, fructose, galactose are...

hexose

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what is the primary source for energy for cell

glucose

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disaccharide

formed by the bonding of two monosaccharides

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polysaccharide

polymers made up of chains of linked monosaccharides

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How can living cells, tissues and polysaccharides be broken down into smaller units

hydrolysis

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examples of nucleic acids

DNA (double stranded) & RNA (single stranded)

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what are four bases in DNA

adenine, thymine, guanine, cytosine

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proteins

important structural components, source of nutrition, speed up metabolic process in the cell.

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polypeptide bonds

are formed in condensation reactions linking amino acids in proteins

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what are amino acids composed of

they are composed of a carbon atom bound to a hydrogen atom and three additional groups - an amino group, carboxyl group, and an R-group

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polypetide

two amino acids joined together; may join to form proteins

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lipids

include fats, phospholipids (in cellular membrane), steroids, terpenes (lipid pigment that operate during photosynthesis)

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what are fats composed of ?

glycerol+ 3 fatty acids

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what are steroid + terpenes composed ?

carbon rings and carbon chains respectively

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fats and oils are composed of what two molecules?

glycerol and fatty acids

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fatty acids

hydrocarbon chain that ends w/ carboxyl group (-COOH)

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Saturated fatty acids

no double bonds between their carbon atoms; carbon chain is saturated with many hydrogen atoms it can hold

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are saturated fatty acids gen solid at room temp?

true

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is fatty acid saturated w/ hydrogen atoms?

false

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true or false: fat molecules are split by hydrolysis for use in cells

true

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phospholipid bilayer

virtually impermeable to charged ions and quite permeable to small lipid soluble molecules

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true or false: molecules move through the membrane at different rates

true

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true or false: small non polar molecules can pass the bilayer w/ least resistance

true (enter by diffusion- form of passive transport)

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diffusion

molecules move from regions of high concentration to areas of low concentration

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Osmosis

movement of the solvent from an area of higher concentration to an area of lower concentration of water.

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carrier proteins

move and change shape to create an opening into the cell.

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true false: large uncharged hydrophobic molecules use the proteins to enter the cell q

true ex. glucose

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is cellular energy required for the facilitated diffusion process

no - its form of passive transport

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reduction

gaining of electrons

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"oxidation" / "reduction"

applied to many reactions involving ions whether or not oxygen is involved ex. NaCl

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true/ false: in NaCl; chlorine is reduced (gaining an electron to form Cl) and sodium is oxidized ( Na loses an electron to form Na+)

true

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when reduction and oxidation are both involed it in a...

redox reaction

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cellular respiration is a....

redox reaction in a biological system; high energy electrons are removed from food molecules which oxidizes them and transferred to increasingly electronegative atoms + help manufacture energy rich molecules used by cells to do work

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disassociation in water

when this happens positive charged hydrogen ion, and negatively charged hydroxide ion (low concentration)

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true/false: hydrogen + hydroxide ions are very reactive

true

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Acid

substances that donate H+ ions when it dissolve or dissociate in water; they increase the concentration of H= ions in water solutions

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true/ false: concentration of OH- ions increases when bases dissolve or dissociate in water

true

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Water w/ equal concentrations of these ions is....

neutral ; pH 7

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pH lower than 7 =

higher concentration of H + ions = acids

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pH higher than 7

lower concentration of H+ ions =bases

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Acids and bases react to form =

water and a salt (ionic compound)

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function of carbs

the primary source of energy for cellular respiration (provides ATP); doesn't provide as much energy as fats because of their hydrophilic groups, easily dissolvable in water.

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carbs are a ...

single chain of carbon atoms to which hydroxyl groups are attached; one carbon is double bonded to oxygen to form a carbonyl group

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3 types of carbs

monosaccharides (one sugar unit), disaccharides (two sugar units), polysaccharides (>3 sugar units)

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monosaccharides

one single sugar molecule; typically linear in dry state but can readily form rings in watery solutions

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example of monosaccharide

glucose, galactose, fructose

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disaccharide

formed when two monosaccharides chemically bond together and a water molecule is given off

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what reaction appends when a water molecule is given off form the bond of monosaccharides

dehydration synthesis/ condensation reaction

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example of disaccharide

glucose + glucose = maltose ("malt sugar") +H2O

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true or false: organisms store metabolic energy contained in glucose by converting it to an insoluble form and depositing it into a specific area

true

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function of polysaccharides

storage of energy and structural support for cells

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examples of storage polysaccharides:

glycogen

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lips are considered(non-polar or polar)

non-polar; insoluble

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function of lipids

long-term energy storage

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lipids are important to the....

cell membrane and chemical signaling , providing protection around organs and insulate the body

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four categories of lipids

triglycerides. phospholipids, steroids, waxes

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